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(4,5-Diazafluoren-9-one-κ(2) N,N′)bis(1H-imidazole-κN (3))bis(thiocyanato-κN)cobalt(II)
In the title complex, [Co(NCS)(2)(C(3)H(4)N(2))(2)(C(11)H(6)N(2)O)], the Co(II) atom has a distorted octahedral coordination with the N atoms of the 4,5-diazafluoren-9-one ligand and two N atoms from imidazole ligands in the equatorial positions and the axial sites occupied by two N atoms of the t...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2011
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200902/ https://www.ncbi.nlm.nih.gov/pubmed/22058833 http://dx.doi.org/10.1107/S1600536811029060 |
| _version_ | 1782214775424417792 |
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| author | Feng, Xiu-Ling Zhang, Yu-Ping |
| author_facet | Feng, Xiu-Ling Zhang, Yu-Ping |
| author_sort | Feng, Xiu-Ling |
| collection | PubMed |
| description | In the title complex, [Co(NCS)(2)(C(3)H(4)N(2))(2)(C(11)H(6)N(2)O)], the Co(II) atom has a distorted octahedral coordination with the N atoms of the 4,5-diazafluoren-9-one ligand and two N atoms from imidazole ligands in the equatorial positions and the axial sites occupied by two N atoms of the thiocyanate ligand. Intermolecular N—H⋯O hydrogen bonding forms a one-dimensional motif parallel to the cell ab diagonal. |
| format | Online Article Text |
| id | pubmed-3200902 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-32009022011-11-06 (4,5-Diazafluoren-9-one-κ(2) N,N′)bis(1H-imidazole-κN (3))bis(thiocyanato-κN)cobalt(II) Feng, Xiu-Ling Zhang, Yu-Ping Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Co(NCS)(2)(C(3)H(4)N(2))(2)(C(11)H(6)N(2)O)], the Co(II) atom has a distorted octahedral coordination with the N atoms of the 4,5-diazafluoren-9-one ligand and two N atoms from imidazole ligands in the equatorial positions and the axial sites occupied by two N atoms of the thiocyanate ligand. Intermolecular N—H⋯O hydrogen bonding forms a one-dimensional motif parallel to the cell ab diagonal. International Union of Crystallography 2011-08-02 /pmc/articles/PMC3200902/ /pubmed/22058833 http://dx.doi.org/10.1107/S1600536811029060 Text en © Feng and Zhang 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Feng, Xiu-Ling Zhang, Yu-Ping (4,5-Diazafluoren-9-one-κ(2) N,N′)bis(1H-imidazole-κN (3))bis(thiocyanato-κN)cobalt(II) |
| title | (4,5-Diazafluoren-9-one-κ(2)
N,N′)bis(1H-imidazole-κN
(3))bis(thiocyanato-κN)cobalt(II) |
| title_full | (4,5-Diazafluoren-9-one-κ(2)
N,N′)bis(1H-imidazole-κN
(3))bis(thiocyanato-κN)cobalt(II) |
| title_fullStr | (4,5-Diazafluoren-9-one-κ(2)
N,N′)bis(1H-imidazole-κN
(3))bis(thiocyanato-κN)cobalt(II) |
| title_full_unstemmed | (4,5-Diazafluoren-9-one-κ(2)
N,N′)bis(1H-imidazole-κN
(3))bis(thiocyanato-κN)cobalt(II) |
| title_short | (4,5-Diazafluoren-9-one-κ(2)
N,N′)bis(1H-imidazole-κN
(3))bis(thiocyanato-κN)cobalt(II) |
| title_sort | (4,5-diazafluoren-9-one-κ(2)
n,n′)bis(1h-imidazole-κn
(3))bis(thiocyanato-κn)cobalt(ii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200902/ https://www.ncbi.nlm.nih.gov/pubmed/22058833 http://dx.doi.org/10.1107/S1600536811029060 |
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