Tris(1,10-phenanthroline)iron(II) μ-oxido-bis­[trichloridoferrate(III)]

In the title salt, [Fe(C(12)H(8)N(2))(3)][Fe(2)Cl(6)O], the ionic components are linked into a two-dimensional supra­molecular layer by two pairs of C—H⋯Cl hydrogen bonds and π–π stacking inter­actions [centroid–centroid distances = 3.655 (4) and 3.498 (3) Å]. The salt is characterized as a mixed-va...

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Detalles Bibliográficos
Autores principales: Ling, Chun, Song, Li, Wang, Xinping
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200904/
https://www.ncbi.nlm.nih.gov/pubmed/22065697
http://dx.doi.org/10.1107/S1600536811031783
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author Ling, Chun
Song, Li
Wang, Xinping
author_facet Ling, Chun
Song, Li
Wang, Xinping
author_sort Ling, Chun
collection PubMed
description In the title salt, [Fe(C(12)H(8)N(2))(3)][Fe(2)Cl(6)O], the ionic components are linked into a two-dimensional supra­molecular layer by two pairs of C—H⋯Cl hydrogen bonds and π–π stacking inter­actions [centroid–centroid distances = 3.655 (4) and 3.498 (3) Å]. The salt is characterized as a mixed-valent Fe(II)–Fe(III) compound, in which an Fe(II) atom is coordinated by three phen ligands, forming a six-coordinated cationic entity and the anionic part is formed by two Fe(III) atoms in tetra­hedral coordination environments constructed by three chloride ions and one bridging oxide ligand. Intra­molecular C—H⋯N hydrogen bonds are observed.
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spelling pubmed-32009042011-11-06 Tris(1,10-phenanthroline)iron(II) μ-oxido-bis­[trichloridoferrate(III)] Ling, Chun Song, Li Wang, Xinping Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title salt, [Fe(C(12)H(8)N(2))(3)][Fe(2)Cl(6)O], the ionic components are linked into a two-dimensional supra­molecular layer by two pairs of C—H⋯Cl hydrogen bonds and π–π stacking inter­actions [centroid–centroid distances = 3.655 (4) and 3.498 (3) Å]. The salt is characterized as a mixed-valent Fe(II)–Fe(III) compound, in which an Fe(II) atom is coordinated by three phen ligands, forming a six-coordinated cationic entity and the anionic part is formed by two Fe(III) atoms in tetra­hedral coordination environments constructed by three chloride ions and one bridging oxide ligand. Intra­molecular C—H⋯N hydrogen bonds are observed. International Union of Crystallography 2011-08-11 /pmc/articles/PMC3200904/ /pubmed/22065697 http://dx.doi.org/10.1107/S1600536811031783 Text en © Ling et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Ling, Chun
Song, Li
Wang, Xinping
Tris(1,10-phenanthroline)iron(II) μ-oxido-bis­[trichloridoferrate(III)]
title Tris(1,10-phenanthroline)iron(II) μ-oxido-bis­[trichloridoferrate(III)]
title_full Tris(1,10-phenanthroline)iron(II) μ-oxido-bis­[trichloridoferrate(III)]
title_fullStr Tris(1,10-phenanthroline)iron(II) μ-oxido-bis­[trichloridoferrate(III)]
title_full_unstemmed Tris(1,10-phenanthroline)iron(II) μ-oxido-bis­[trichloridoferrate(III)]
title_short Tris(1,10-phenanthroline)iron(II) μ-oxido-bis­[trichloridoferrate(III)]
title_sort tris(1,10-phenanthroline)iron(ii) μ-oxido-bis­[trichloridoferrate(iii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200904/
https://www.ncbi.nlm.nih.gov/pubmed/22065697
http://dx.doi.org/10.1107/S1600536811031783
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