{2,2′-[(2,2-Dimethyl­propane-1,3-diyl­dinitrilo)­bis­(phenyl­methyl­idyne)]­diphenolato}nickel(II)

The asymmetric unit of the title complex, [Ni(C(31)H(28)N(2)O(2))], comprises two crystallographically independent mol­ecules. The geometry around the Ni(II) atom in each mol­ecule is distorted square planar. The dihedral angles between the two phen­oxy rings in each mol­ecule are 17.8 (4) and 36.5 ...

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Autores principales: Kargar, Hadi, Kia, Reza, Moghadam, Majid, Froozandeh, Fatemeh, Tahir, Muhammad Nawaz
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200906/
https://www.ncbi.nlm.nih.gov/pubmed/22065816
http://dx.doi.org/10.1107/S1600536811029813
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author Kargar, Hadi
Kia, Reza
Moghadam, Majid
Froozandeh, Fatemeh
Tahir, Muhammad Nawaz
author_facet Kargar, Hadi
Kia, Reza
Moghadam, Majid
Froozandeh, Fatemeh
Tahir, Muhammad Nawaz
author_sort Kargar, Hadi
collection PubMed
description The asymmetric unit of the title complex, [Ni(C(31)H(28)N(2)O(2))], comprises two crystallographically independent mol­ecules. The geometry around the Ni(II) atom in each mol­ecule is distorted square planar. The dihedral angles between the two phen­oxy rings in each mol­ecule are 17.8 (4) and 36.5 (4)°. The crystal packing is stabilized by weak π–π inter­actions [centroid–centroid distance = 3.758 (5) Å] and C—H⋯π inter­actions.
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spelling pubmed-32009062011-11-06 {2,2′-[(2,2-Dimethyl­propane-1,3-diyl­dinitrilo)­bis­(phenyl­methyl­idyne)]­diphenolato}nickel(II) Kargar, Hadi Kia, Reza Moghadam, Majid Froozandeh, Fatemeh Tahir, Muhammad Nawaz Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title complex, [Ni(C(31)H(28)N(2)O(2))], comprises two crystallographically independent mol­ecules. The geometry around the Ni(II) atom in each mol­ecule is distorted square planar. The dihedral angles between the two phen­oxy rings in each mol­ecule are 17.8 (4) and 36.5 (4)°. The crystal packing is stabilized by weak π–π inter­actions [centroid–centroid distance = 3.758 (5) Å] and C—H⋯π inter­actions. International Union of Crystallography 2011-08-02 /pmc/articles/PMC3200906/ /pubmed/22065816 http://dx.doi.org/10.1107/S1600536811029813 Text en © Kargar et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Kargar, Hadi
Kia, Reza
Moghadam, Majid
Froozandeh, Fatemeh
Tahir, Muhammad Nawaz
{2,2′-[(2,2-Dimethyl­propane-1,3-diyl­dinitrilo)­bis­(phenyl­methyl­idyne)]­diphenolato}nickel(II)
title {2,2′-[(2,2-Dimethyl­propane-1,3-diyl­dinitrilo)­bis­(phenyl­methyl­idyne)]­diphenolato}nickel(II)
title_full {2,2′-[(2,2-Dimethyl­propane-1,3-diyl­dinitrilo)­bis­(phenyl­methyl­idyne)]­diphenolato}nickel(II)
title_fullStr {2,2′-[(2,2-Dimethyl­propane-1,3-diyl­dinitrilo)­bis­(phenyl­methyl­idyne)]­diphenolato}nickel(II)
title_full_unstemmed {2,2′-[(2,2-Dimethyl­propane-1,3-diyl­dinitrilo)­bis­(phenyl­methyl­idyne)]­diphenolato}nickel(II)
title_short {2,2′-[(2,2-Dimethyl­propane-1,3-diyl­dinitrilo)­bis­(phenyl­methyl­idyne)]­diphenolato}nickel(II)
title_sort {2,2′-[(2,2-dimethyl­propane-1,3-diyl­dinitrilo)­bis­(phenyl­methyl­idyne)]­diphenolato}nickel(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200906/
https://www.ncbi.nlm.nih.gov/pubmed/22065816
http://dx.doi.org/10.1107/S1600536811029813
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