trans-Carbonyl­chloridobis[dicyclo­hex­yl(4-isopropyl­phen­yl)phosphane]rhodium(I) acetone monosolvate

The title rhodium Vaska-type complex, trans-[RhCl{P(C(6)H(11))(2)(C(6)H(4)-4-C(3)H(7))(2)}(2)(CO)], crystallizes with an accompanying acetone solvent mol­ecule. The metal atom shows a distorted square-planar coordination environment with selected important geometrical parameters of Rh—P = 2.3237 (6)...

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Autores principales: Makhoba, Sizwe, Muller, Alfred, Meijboom, Reinout, Omondi, Bernard
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200912/
https://www.ncbi.nlm.nih.gov/pubmed/22058880
http://dx.doi.org/10.1107/S1600536811033447
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author Makhoba, Sizwe
Muller, Alfred
Meijboom, Reinout
Omondi, Bernard
author_facet Makhoba, Sizwe
Muller, Alfred
Meijboom, Reinout
Omondi, Bernard
author_sort Makhoba, Sizwe
collection PubMed
description The title rhodium Vaska-type complex, trans-[RhCl{P(C(6)H(11))(2)(C(6)H(4)-4-C(3)H(7))(2)}(2)(CO)], crystallizes with an accompanying acetone solvent mol­ecule. The metal atom shows a distorted square-planar coordination environment with selected important geometrical parameters of Rh—P = 2.3237 (6) and 2.3253 (6) Å, Rh—Cl = 2.3724 (6) Å, Rh—C = 1.802 (2) Å, P—Rh—P = 173.42 (2)° and Cl—Rh—C = 179.13 (7)°. Effective cone angles for the two P atoms are 165 and 161°, respectively. Both isopropyl groups and the acetone mol­ecule are disordered with occupancy values of 0.523 (5):0.477 (5), 0.554 (8):0.446 (8) and 0.735 (4):0.265 (4), respectively. The crystal packing is stabilized by weak C—H⋯O and C—H⋯Cl contacts.
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spelling pubmed-32009122011-11-06 trans-Carbonyl­chloridobis[dicyclo­hex­yl(4-isopropyl­phen­yl)phosphane]rhodium(I) acetone monosolvate Makhoba, Sizwe Muller, Alfred Meijboom, Reinout Omondi, Bernard Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title rhodium Vaska-type complex, trans-[RhCl{P(C(6)H(11))(2)(C(6)H(4)-4-C(3)H(7))(2)}(2)(CO)], crystallizes with an accompanying acetone solvent mol­ecule. The metal atom shows a distorted square-planar coordination environment with selected important geometrical parameters of Rh—P = 2.3237 (6) and 2.3253 (6) Å, Rh—Cl = 2.3724 (6) Å, Rh—C = 1.802 (2) Å, P—Rh—P = 173.42 (2)° and Cl—Rh—C = 179.13 (7)°. Effective cone angles for the two P atoms are 165 and 161°, respectively. Both isopropyl groups and the acetone mol­ecule are disordered with occupancy values of 0.523 (5):0.477 (5), 0.554 (8):0.446 (8) and 0.735 (4):0.265 (4), respectively. The crystal packing is stabilized by weak C—H⋯O and C—H⋯Cl contacts. International Union of Crystallography 2011-08-27 /pmc/articles/PMC3200912/ /pubmed/22058880 http://dx.doi.org/10.1107/S1600536811033447 Text en © Makhoba et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Makhoba, Sizwe
Muller, Alfred
Meijboom, Reinout
Omondi, Bernard
trans-Carbonyl­chloridobis[dicyclo­hex­yl(4-isopropyl­phen­yl)phosphane]rhodium(I) acetone monosolvate
title trans-Carbonyl­chloridobis[dicyclo­hex­yl(4-isopropyl­phen­yl)phosphane]rhodium(I) acetone monosolvate
title_full trans-Carbonyl­chloridobis[dicyclo­hex­yl(4-isopropyl­phen­yl)phosphane]rhodium(I) acetone monosolvate
title_fullStr trans-Carbonyl­chloridobis[dicyclo­hex­yl(4-isopropyl­phen­yl)phosphane]rhodium(I) acetone monosolvate
title_full_unstemmed trans-Carbonyl­chloridobis[dicyclo­hex­yl(4-isopropyl­phen­yl)phosphane]rhodium(I) acetone monosolvate
title_short trans-Carbonyl­chloridobis[dicyclo­hex­yl(4-isopropyl­phen­yl)phosphane]rhodium(I) acetone monosolvate
title_sort trans-carbonyl­chloridobis[dicyclo­hex­yl(4-isopropyl­phen­yl)phosphane]rhodium(i) acetone monosolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200912/
https://www.ncbi.nlm.nih.gov/pubmed/22058880
http://dx.doi.org/10.1107/S1600536811033447
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AT mulleralfred transcarbonylchloridobisdicyclohexyl4isopropylphenylphosphanerhodiumiacetonemonosolvate
AT meijboomreinout transcarbonylchloridobisdicyclohexyl4isopropylphenylphosphanerhodiumiacetonemonosolvate
AT omondibernard transcarbonylchloridobisdicyclohexyl4isopropylphenylphosphanerhodiumiacetonemonosolvate

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