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8-(Naphthalen-1-yl)quinoline
In the title molecule, C(19)H(13)N, the angle between the mean planes of the naphthalene and quinoline ring systems is 68.59 (2)°. The compound is of interest with respect to its potential for spontaneous resolution. In the crystal structure, the R and S isomers are arranged in alternating homochi...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200913/ https://www.ncbi.nlm.nih.gov/pubmed/22059059 http://dx.doi.org/10.1107/S1600536811034052 |
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author | Kanu, Godwin Lalancette, Roger A. Vitale, Dale E. |
author_facet | Kanu, Godwin Lalancette, Roger A. Vitale, Dale E. |
author_sort | Kanu, Godwin |
collection | PubMed |
description | In the title molecule, C(19)H(13)N, the angle between the mean planes of the naphthalene and quinoline ring systems is 68.59 (2)°. The compound is of interest with respect to its potential for spontaneous resolution. In the crystal structure, the R and S isomers are arranged in alternating homochiral layers. The molecules of a given layer are oriented with their major axes (i.e. the axis perpendicular to the interannular bond) in the same direction and their naphthalene and quinoline ring systems are arranged parallel. Like the configurations, this orientation alternates in adjacent layers. |
format | Online Article Text |
id | pubmed-3200913 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32009132011-11-06 8-(Naphthalen-1-yl)quinoline Kanu, Godwin Lalancette, Roger A. Vitale, Dale E. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title molecule, C(19)H(13)N, the angle between the mean planes of the naphthalene and quinoline ring systems is 68.59 (2)°. The compound is of interest with respect to its potential for spontaneous resolution. In the crystal structure, the R and S isomers are arranged in alternating homochiral layers. The molecules of a given layer are oriented with their major axes (i.e. the axis perpendicular to the interannular bond) in the same direction and their naphthalene and quinoline ring systems are arranged parallel. Like the configurations, this orientation alternates in adjacent layers. International Union of Crystallography 2011-08-31 /pmc/articles/PMC3200913/ /pubmed/22059059 http://dx.doi.org/10.1107/S1600536811034052 Text en © Kanu et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Kanu, Godwin Lalancette, Roger A. Vitale, Dale E. 8-(Naphthalen-1-yl)quinoline |
title | 8-(Naphthalen-1-yl)quinoline |
title_full | 8-(Naphthalen-1-yl)quinoline |
title_fullStr | 8-(Naphthalen-1-yl)quinoline |
title_full_unstemmed | 8-(Naphthalen-1-yl)quinoline |
title_short | 8-(Naphthalen-1-yl)quinoline |
title_sort | 8-(naphthalen-1-yl)quinoline |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200913/ https://www.ncbi.nlm.nih.gov/pubmed/22059059 http://dx.doi.org/10.1107/S1600536811034052 |
work_keys_str_mv | AT kanugodwin 8naphthalen1ylquinoline AT lalancetterogera 8naphthalen1ylquinoline AT vitaledalee 8naphthalen1ylquinoline |