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trans-Diaquabis[4-carboxy-5-carboxylato-2-(pyridin-1-ium-4-yl)-1H-imidazol-1-ido-κ(2) N (1),O (5)]cobalt(II)
In the title compound, [Co(C(10)H(6)N(3)O(4))(2)(H(2)O)(2)], the Co(II) ion is coordinated by two O atoms of two water molecules, two imidazole nitrogen atoms and two carboxylate O atoms of the two trans-standing chelate ligands, displaying a distorted octahedral coordination geometry. A three-d...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200914/ https://www.ncbi.nlm.nih.gov/pubmed/22058867 http://dx.doi.org/10.1107/S1600536811032545 |
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author | Sun, Lin Huang, Yu Hua Chen, Ting Ting Deng, Hong |
author_facet | Sun, Lin Huang, Yu Hua Chen, Ting Ting Deng, Hong |
author_sort | Sun, Lin |
collection | PubMed |
description | In the title compound, [Co(C(10)H(6)N(3)O(4))(2)(H(2)O)(2)], the Co(II) ion is coordinated by two O atoms of two water molecules, two imidazole nitrogen atoms and two carboxylate O atoms of the two trans-standing chelate ligands, displaying a distorted octahedral coordination geometry. A three-dimensional supramolecular framework is generated through N—H⋯O, O—H⋯N and O—H⋯O hydrogen-bonding interactions. |
format | Online Article Text |
id | pubmed-3200914 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32009142011-11-06 trans-Diaquabis[4-carboxy-5-carboxylato-2-(pyridin-1-ium-4-yl)-1H-imidazol-1-ido-κ(2) N (1),O (5)]cobalt(II) Sun, Lin Huang, Yu Hua Chen, Ting Ting Deng, Hong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Co(C(10)H(6)N(3)O(4))(2)(H(2)O)(2)], the Co(II) ion is coordinated by two O atoms of two water molecules, two imidazole nitrogen atoms and two carboxylate O atoms of the two trans-standing chelate ligands, displaying a distorted octahedral coordination geometry. A three-dimensional supramolecular framework is generated through N—H⋯O, O—H⋯N and O—H⋯O hydrogen-bonding interactions. International Union of Crystallography 2011-08-17 /pmc/articles/PMC3200914/ /pubmed/22058867 http://dx.doi.org/10.1107/S1600536811032545 Text en © Sun et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Sun, Lin Huang, Yu Hua Chen, Ting Ting Deng, Hong trans-Diaquabis[4-carboxy-5-carboxylato-2-(pyridin-1-ium-4-yl)-1H-imidazol-1-ido-κ(2) N (1),O (5)]cobalt(II) |
title |
trans-Diaquabis[4-carboxy-5-carboxylato-2-(pyridin-1-ium-4-yl)-1H-imidazol-1-ido-κ(2)
N
(1),O
(5)]cobalt(II) |
title_full |
trans-Diaquabis[4-carboxy-5-carboxylato-2-(pyridin-1-ium-4-yl)-1H-imidazol-1-ido-κ(2)
N
(1),O
(5)]cobalt(II) |
title_fullStr |
trans-Diaquabis[4-carboxy-5-carboxylato-2-(pyridin-1-ium-4-yl)-1H-imidazol-1-ido-κ(2)
N
(1),O
(5)]cobalt(II) |
title_full_unstemmed |
trans-Diaquabis[4-carboxy-5-carboxylato-2-(pyridin-1-ium-4-yl)-1H-imidazol-1-ido-κ(2)
N
(1),O
(5)]cobalt(II) |
title_short |
trans-Diaquabis[4-carboxy-5-carboxylato-2-(pyridin-1-ium-4-yl)-1H-imidazol-1-ido-κ(2)
N
(1),O
(5)]cobalt(II) |
title_sort | trans-diaquabis[4-carboxy-5-carboxylato-2-(pyridin-1-ium-4-yl)-1h-imidazol-1-ido-κ(2)
n
(1),o
(5)]cobalt(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200914/ https://www.ncbi.nlm.nih.gov/pubmed/22058867 http://dx.doi.org/10.1107/S1600536811032545 |
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