A cationic rhodium(I) N-heterocyclic carbene complex isolated as an aqua adduct

The title complex, aqua­[1,3-bis­(2,6-diiso­propyl­phen­yl)imid­az­ol-2-yl­idene](η(4)-cyclo­octa-1,5-diene)rhodium(I) tetra­fluor­ido­borate, [Rh(C(8)H(12))(C(27)H(36)N(2))(H(2)O)]BF(4), exihibits a square-planar geometry around the Rh(I) atom, formed by a bidentate cyclo­octa-1,5-diene (cod) ligan...

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Detalles Bibliográficos
Autores principales: Huttenstine, Ashley L., Rajaseelan, Edward, Oliver, Allen G., Rood, Jeffrey A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200919/
https://www.ncbi.nlm.nih.gov/pubmed/22058874
http://dx.doi.org/10.1107/S1600536811033125
Descripción
Sumario:The title complex, aqua­[1,3-bis­(2,6-diiso­propyl­phen­yl)imid­az­ol-2-yl­idene](η(4)-cyclo­octa-1,5-diene)rhodium(I) tetra­fluor­ido­borate, [Rh(C(8)H(12))(C(27)H(36)N(2))(H(2)O)]BF(4), exihibits a square-planar geometry around the Rh(I) atom, formed by a bidentate cyclo­octa-1,5-diene (cod) ligand, an N-heterocylcic carbene and an aqua ligand. The complex is cationic and a BF(4) (−) anion balances the charge. The structure exists as a hydrogen-bonded dimer in the solid state, formed via inter­actions between the aqua ligand H atoms and the BF(4) (−) F atoms.

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