A cationic rhodium(I) N-heterocyclic carbene complex isolated as an aqua adduct

The title complex, aqua­[1,3-bis­(2,6-diiso­propyl­phen­yl)imid­az­ol-2-yl­idene](η(4)-cyclo­octa-1,5-diene)rhodium(I) tetra­fluor­ido­borate, [Rh(C(8)H(12))(C(27)H(36)N(2))(H(2)O)]BF(4), exihibits a square-planar geometry around the Rh(I) atom, formed by a bidentate cyclo­octa-1,5-diene (cod) ligan...

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Autores principales: Huttenstine, Ashley L., Rajaseelan, Edward, Oliver, Allen G., Rood, Jeffrey A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200919/
https://www.ncbi.nlm.nih.gov/pubmed/22058874
http://dx.doi.org/10.1107/S1600536811033125
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author Huttenstine, Ashley L.
Rajaseelan, Edward
Oliver, Allen G.
Rood, Jeffrey A.
author_facet Huttenstine, Ashley L.
Rajaseelan, Edward
Oliver, Allen G.
Rood, Jeffrey A.
author_sort Huttenstine, Ashley L.
collection PubMed
description The title complex, aqua­[1,3-bis­(2,6-diiso­propyl­phen­yl)imid­az­ol-2-yl­idene](η(4)-cyclo­octa-1,5-diene)rhodium(I) tetra­fluor­ido­borate, [Rh(C(8)H(12))(C(27)H(36)N(2))(H(2)O)]BF(4), exihibits a square-planar geometry around the Rh(I) atom, formed by a bidentate cyclo­octa-1,5-diene (cod) ligand, an N-heterocylcic carbene and an aqua ligand. The complex is cationic and a BF(4) (−) anion balances the charge. The structure exists as a hydrogen-bonded dimer in the solid state, formed via inter­actions between the aqua ligand H atoms and the BF(4) (−) F atoms.
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spelling pubmed-32009192011-11-06 A cationic rhodium(I) N-heterocyclic carbene complex isolated as an aqua adduct Huttenstine, Ashley L. Rajaseelan, Edward Oliver, Allen G. Rood, Jeffrey A. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, aqua­[1,3-bis­(2,6-diiso­propyl­phen­yl)imid­az­ol-2-yl­idene](η(4)-cyclo­octa-1,5-diene)rhodium(I) tetra­fluor­ido­borate, [Rh(C(8)H(12))(C(27)H(36)N(2))(H(2)O)]BF(4), exihibits a square-planar geometry around the Rh(I) atom, formed by a bidentate cyclo­octa-1,5-diene (cod) ligand, an N-heterocylcic carbene and an aqua ligand. The complex is cationic and a BF(4) (−) anion balances the charge. The structure exists as a hydrogen-bonded dimer in the solid state, formed via inter­actions between the aqua ligand H atoms and the BF(4) (−) F atoms. International Union of Crystallography 2011-08-27 /pmc/articles/PMC3200919/ /pubmed/22058874 http://dx.doi.org/10.1107/S1600536811033125 Text en © Huttenstine et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Huttenstine, Ashley L.
Rajaseelan, Edward
Oliver, Allen G.
Rood, Jeffrey A.
A cationic rhodium(I) N-heterocyclic carbene complex isolated as an aqua adduct
title A cationic rhodium(I) N-heterocyclic carbene complex isolated as an aqua adduct
title_full A cationic rhodium(I) N-heterocyclic carbene complex isolated as an aqua adduct
title_fullStr A cationic rhodium(I) N-heterocyclic carbene complex isolated as an aqua adduct
title_full_unstemmed A cationic rhodium(I) N-heterocyclic carbene complex isolated as an aqua adduct
title_short A cationic rhodium(I) N-heterocyclic carbene complex isolated as an aqua adduct
title_sort cationic rhodium(i) n-heterocyclic carbene complex isolated as an aqua adduct
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200919/
https://www.ncbi.nlm.nih.gov/pubmed/22058874
http://dx.doi.org/10.1107/S1600536811033125
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