trans-Tetra­carbonyl­bis­[tris­(4-fluoro­phen­yl)phosphane-κP]chromium(0)

In the title compound, [Cr(C(18)H(12)F(3)P)(2)(CO)(4)], the Cr atom is octa­hedrally coordinated by four carbonyl ligands and the two tertiary phosphanes that are trans to each other. The Cr atom and two carbonyl groups are on a twofold axis. The benzene rings attached to the phospho­rus atom make d...

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Detalles Bibliográficos
Autores principales: Norlidah, M. N., Hamdya, F. M. Y., Bin Shawkataly, Omar, Rosli, Mohd Mustaqim, Fun, Hoong-Kun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200925/
https://www.ncbi.nlm.nih.gov/pubmed/22064845
http://dx.doi.org/10.1107/S1600536811033939
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author Norlidah, M. N.
Hamdya, F. M. Y.
Bin Shawkataly, Omar
Rosli, Mohd Mustaqim
Fun, Hoong-Kun
author_facet Norlidah, M. N.
Hamdya, F. M. Y.
Bin Shawkataly, Omar
Rosli, Mohd Mustaqim
Fun, Hoong-Kun
author_sort Norlidah, M. N.
collection PubMed
description In the title compound, [Cr(C(18)H(12)F(3)P)(2)(CO)(4)], the Cr atom is octa­hedrally coordinated by four carbonyl ligands and the two tertiary phosphanes that are trans to each other. The Cr atom and two carbonyl groups are on a twofold axis. The benzene rings attached to the phospho­rus atom make dihedral angles of 80.32 (5), 52.91 (5) and 83.80 (5)° with each other. In the crystal, C—H⋯O and C—H⋯F inter­molecular inter­actions form an infinite three-dimensional network.
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spelling pubmed-32009252011-11-06 trans-Tetra­carbonyl­bis­[tris­(4-fluoro­phen­yl)phosphane-κP]chromium(0) Norlidah, M. N. Hamdya, F. M. Y. Bin Shawkataly, Omar Rosli, Mohd Mustaqim Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cr(C(18)H(12)F(3)P)(2)(CO)(4)], the Cr atom is octa­hedrally coordinated by four carbonyl ligands and the two tertiary phosphanes that are trans to each other. The Cr atom and two carbonyl groups are on a twofold axis. The benzene rings attached to the phospho­rus atom make dihedral angles of 80.32 (5), 52.91 (5) and 83.80 (5)° with each other. In the crystal, C—H⋯O and C—H⋯F inter­molecular inter­actions form an infinite three-dimensional network. International Union of Crystallography 2011-08-27 /pmc/articles/PMC3200925/ /pubmed/22064845 http://dx.doi.org/10.1107/S1600536811033939 Text en © Norlidah et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Norlidah, M. N.
Hamdya, F. M. Y.
Bin Shawkataly, Omar
Rosli, Mohd Mustaqim
Fun, Hoong-Kun
trans-Tetra­carbonyl­bis­[tris­(4-fluoro­phen­yl)phosphane-κP]chromium(0)
title trans-Tetra­carbonyl­bis­[tris­(4-fluoro­phen­yl)phosphane-κP]chromium(0)
title_full trans-Tetra­carbonyl­bis­[tris­(4-fluoro­phen­yl)phosphane-κP]chromium(0)
title_fullStr trans-Tetra­carbonyl­bis­[tris­(4-fluoro­phen­yl)phosphane-κP]chromium(0)
title_full_unstemmed trans-Tetra­carbonyl­bis­[tris­(4-fluoro­phen­yl)phosphane-κP]chromium(0)
title_short trans-Tetra­carbonyl­bis­[tris­(4-fluoro­phen­yl)phosphane-κP]chromium(0)
title_sort trans-tetra­carbonyl­bis­[tris­(4-fluoro­phen­yl)phosphane-κp]chromium(0)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200925/
https://www.ncbi.nlm.nih.gov/pubmed/22064845
http://dx.doi.org/10.1107/S1600536811033939
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