Dibromido(4,7-diazadecane-1,10-di­amine)­copper(II)

In the title compound, [CuBr(2)(C(8)H(22)N(4))], the Cu(II) atom is six-coordinate forming a distorted octa­hedral complex and is bonded to two axial bromide anions and four equatorial nitro­gen donors. The equatorial Cu—N bond distances range from 2.005 (8) to 2.046 (8) Å while the axial Cu—Br dist...

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Detalles Bibliográficos
Autores principales: Assey, Gervas E., Butcher, Ray J., Gultneh, Yilma
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200928/
https://www.ncbi.nlm.nih.gov/pubmed/22064899
http://dx.doi.org/10.1107/S160053681103251X
Descripción
Sumario:In the title compound, [CuBr(2)(C(8)H(22)N(4))], the Cu(II) atom is six-coordinate forming a distorted octa­hedral complex and is bonded to two axial bromide anions and four equatorial nitro­gen donors. The equatorial Cu—N bond distances range from 2.005 (8) to 2.046 (8) Å while the axial Cu—Br distances are 2.8616 (17) and 2.9402 (17) Å, thus the six-coordinate Cu complex shows the usual Jahn–Teller distortion. All amine hydrogen atoms participate in either inter- or intra­molecular hydrogen bonding to the Br anions.

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