Dibromido(4,7-diazadecane-1,10-di­amine)­copper(II)

In the title compound, [CuBr(2)(C(8)H(22)N(4))], the Cu(II) atom is six-coordinate forming a distorted octa­hedral complex and is bonded to two axial bromide anions and four equatorial nitro­gen donors. The equatorial Cu—N bond distances range from 2.005 (8) to 2.046 (8) Å while the axial Cu—Br dist...

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Detalles Bibliográficos
Autores principales: Assey, Gervas E., Butcher, Ray J., Gultneh, Yilma
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200928/
https://www.ncbi.nlm.nih.gov/pubmed/22064899
http://dx.doi.org/10.1107/S160053681103251X
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author Assey, Gervas E.
Butcher, Ray J.
Gultneh, Yilma
author_facet Assey, Gervas E.
Butcher, Ray J.
Gultneh, Yilma
author_sort Assey, Gervas E.
collection PubMed
description In the title compound, [CuBr(2)(C(8)H(22)N(4))], the Cu(II) atom is six-coordinate forming a distorted octa­hedral complex and is bonded to two axial bromide anions and four equatorial nitro­gen donors. The equatorial Cu—N bond distances range from 2.005 (8) to 2.046 (8) Å while the axial Cu—Br distances are 2.8616 (17) and 2.9402 (17) Å, thus the six-coordinate Cu complex shows the usual Jahn–Teller distortion. All amine hydrogen atoms participate in either inter- or intra­molecular hydrogen bonding to the Br anions.
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spelling pubmed-32009282011-11-06 Dibromido(4,7-diazadecane-1,10-di­amine)­copper(II) Assey, Gervas E. Butcher, Ray J. Gultneh, Yilma Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [CuBr(2)(C(8)H(22)N(4))], the Cu(II) atom is six-coordinate forming a distorted octa­hedral complex and is bonded to two axial bromide anions and four equatorial nitro­gen donors. The equatorial Cu—N bond distances range from 2.005 (8) to 2.046 (8) Å while the axial Cu—Br distances are 2.8616 (17) and 2.9402 (17) Å, thus the six-coordinate Cu complex shows the usual Jahn–Teller distortion. All amine hydrogen atoms participate in either inter- or intra­molecular hydrogen bonding to the Br anions. International Union of Crystallography 2011-08-17 /pmc/articles/PMC3200928/ /pubmed/22064899 http://dx.doi.org/10.1107/S160053681103251X Text en © Assey et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Assey, Gervas E.
Butcher, Ray J.
Gultneh, Yilma
Dibromido(4,7-diazadecane-1,10-di­amine)­copper(II)
title Dibromido(4,7-diazadecane-1,10-di­amine)­copper(II)
title_full Dibromido(4,7-diazadecane-1,10-di­amine)­copper(II)
title_fullStr Dibromido(4,7-diazadecane-1,10-di­amine)­copper(II)
title_full_unstemmed Dibromido(4,7-diazadecane-1,10-di­amine)­copper(II)
title_short Dibromido(4,7-diazadecane-1,10-di­amine)­copper(II)
title_sort dibromido(4,7-diazadecane-1,10-di­amine)­copper(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200928/
https://www.ncbi.nlm.nih.gov/pubmed/22064899
http://dx.doi.org/10.1107/S160053681103251X
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