Cargando…
rac-Phenyl (benzylamido)(p-tolylamido)phosphinate
The title compound, C(20)H(21)N(2)O(2)P, was synthesized from (RS)-(C(6)H(5)O)P(O)Cl(NHC(6)H(4)-p-CH(3)) and benzylamine. The product crystallizes as a racemate in a polar space group. The phosphorus atom has a distorted tetrahedral configuration: the bond angles at the P atom are in the range 10...
Autores principales: | , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200931/ https://www.ncbi.nlm.nih.gov/pubmed/22059060 http://dx.doi.org/10.1107/S1600536811034465 |
Sumario: | The title compound, C(20)H(21)N(2)O(2)P, was synthesized from (RS)-(C(6)H(5)O)P(O)Cl(NHC(6)H(4)-p-CH(3)) and benzylamine. The product crystallizes as a racemate in a polar space group. The phosphorus atom has a distorted tetrahedral configuration: the bond angles at the P atom are in the range 103.2 (1)–118.4 (1)°. The P—N(benzylamido) bond [1.615 (2) Å] is slightly shorter than the P—N(p-tolylamido) bond [1.630 (2) Å]. Both N—H groups adopt an anti orientation relative to the phosphoryl group. In the crystal, the adjacent molecules are linked via N—H⋯O hydrogen bonds, forming R (2) (2)(8) rings, into a one-dimensional arrangement parallel to the x axis. |
---|