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rac-Phenyl (benzylamido)(p-tolyl­amido)­phosphinate

The title compound, C(20)H(21)N(2)O(2)P, was synthesized from (RS)-(C(6)H(5)O)P(O)Cl(NHC(6)H(4)-p-CH(3)) and benzyl­amine. The product crystallizes as a racemate in a polar space group. The phospho­rus atom has a distorted tetra­hedral configuration: the bond angles at the P atom are in the range 10...

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Detalles Bibliográficos
Autores principales: Pourayoubi, Mehrdad, Karimi Ahmadabad, Fatemeh, Nečas, Marek
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200931/
https://www.ncbi.nlm.nih.gov/pubmed/22059060
http://dx.doi.org/10.1107/S1600536811034465
Descripción
Sumario:The title compound, C(20)H(21)N(2)O(2)P, was synthesized from (RS)-(C(6)H(5)O)P(O)Cl(NHC(6)H(4)-p-CH(3)) and benzyl­amine. The product crystallizes as a racemate in a polar space group. The phospho­rus atom has a distorted tetra­hedral configuration: the bond angles at the P atom are in the range 103.2 (1)–118.4 (1)°. The P—N(benzyl­amido) bond [1.615 (2) Å] is slightly shorter than the P—N(p-tolyl­amido) bond [1.630 (2) Å]. Both N—H groups adopt an anti orientation relative to the phosphoryl group. In the crystal, the adjacent mol­ecules are linked via N—H⋯O hydrogen bonds, forming R (2) (2)(8) rings, into a one-dimensional arrangement parallel to the x axis.