rac-Phenyl (benzylamido)(p-tolyl­amido)­phosphinate

The title compound, C(20)H(21)N(2)O(2)P, was synthesized from (RS)-(C(6)H(5)O)P(O)Cl(NHC(6)H(4)-p-CH(3)) and benzyl­amine. The product crystallizes as a racemate in a polar space group. The phospho­rus atom has a distorted tetra­hedral configuration: the bond angles at the P atom are in the range 10...

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Detalles Bibliográficos
Autores principales: Pourayoubi, Mehrdad, Karimi Ahmadabad, Fatemeh, Nečas, Marek
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200931/
https://www.ncbi.nlm.nih.gov/pubmed/22059060
http://dx.doi.org/10.1107/S1600536811034465
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author Pourayoubi, Mehrdad
Karimi Ahmadabad, Fatemeh
Nečas, Marek
author_facet Pourayoubi, Mehrdad
Karimi Ahmadabad, Fatemeh
Nečas, Marek
author_sort Pourayoubi, Mehrdad
collection PubMed
description The title compound, C(20)H(21)N(2)O(2)P, was synthesized from (RS)-(C(6)H(5)O)P(O)Cl(NHC(6)H(4)-p-CH(3)) and benzyl­amine. The product crystallizes as a racemate in a polar space group. The phospho­rus atom has a distorted tetra­hedral configuration: the bond angles at the P atom are in the range 103.2 (1)–118.4 (1)°. The P—N(benzyl­amido) bond [1.615 (2) Å] is slightly shorter than the P—N(p-tolyl­amido) bond [1.630 (2) Å]. Both N—H groups adopt an anti orientation relative to the phosphoryl group. In the crystal, the adjacent mol­ecules are linked via N—H⋯O hydrogen bonds, forming R (2) (2)(8) rings, into a one-dimensional arrangement parallel to the x axis.
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spelling pubmed-32009312011-11-06 rac-Phenyl (benzylamido)(p-tolyl­amido)­phosphinate Pourayoubi, Mehrdad Karimi Ahmadabad, Fatemeh Nečas, Marek Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(20)H(21)N(2)O(2)P, was synthesized from (RS)-(C(6)H(5)O)P(O)Cl(NHC(6)H(4)-p-CH(3)) and benzyl­amine. The product crystallizes as a racemate in a polar space group. The phospho­rus atom has a distorted tetra­hedral configuration: the bond angles at the P atom are in the range 103.2 (1)–118.4 (1)°. The P—N(benzyl­amido) bond [1.615 (2) Å] is slightly shorter than the P—N(p-tolyl­amido) bond [1.630 (2) Å]. Both N—H groups adopt an anti orientation relative to the phosphoryl group. In the crystal, the adjacent mol­ecules are linked via N—H⋯O hydrogen bonds, forming R (2) (2)(8) rings, into a one-dimensional arrangement parallel to the x axis. International Union of Crystallography 2011-08-31 /pmc/articles/PMC3200931/ /pubmed/22059060 http://dx.doi.org/10.1107/S1600536811034465 Text en © Pourayoubi et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Pourayoubi, Mehrdad
Karimi Ahmadabad, Fatemeh
Nečas, Marek
rac-Phenyl (benzylamido)(p-tolyl­amido)­phosphinate
title rac-Phenyl (benzylamido)(p-tolyl­amido)­phosphinate
title_full rac-Phenyl (benzylamido)(p-tolyl­amido)­phosphinate
title_fullStr rac-Phenyl (benzylamido)(p-tolyl­amido)­phosphinate
title_full_unstemmed rac-Phenyl (benzylamido)(p-tolyl­amido)­phosphinate
title_short rac-Phenyl (benzylamido)(p-tolyl­amido)­phosphinate
title_sort rac-phenyl (benzylamido)(p-tolyl­amido)­phosphinate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200931/
https://www.ncbi.nlm.nih.gov/pubmed/22059060
http://dx.doi.org/10.1107/S1600536811034465
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AT karimiahmadabadfatemeh racphenylbenzylamidoptolylamidophosphinate
AT necasmarek racphenylbenzylamidoptolylamidophosphinate

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