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3-Amino-1-(2H-1,3-benzodioxol-5-yl)-9,10-dihydrophenanthrene-2,4-dicarbonitrile
In the title compound, C(23)H(15)N(3)O(2), significant deviations from planarity are evidenced in the values of the dihedral angles formed between the amino-benzene ring and the benzene rings of the 1,3-benzodioxole [65.38 (12)°] and 1,2-dihydronaphthalene [26.27 (14)°] residues; the dioxole ring h...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2011
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200934/ https://www.ncbi.nlm.nih.gov/pubmed/22059011 http://dx.doi.org/10.1107/S1600536811033563 |
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| author | Asiri, Abdullah M. Al-Youbi, Abdulrahman O. Faidallah, Hassan M. Ng, Seik Weng Tiekink, Edward R. T. |
| author_facet | Asiri, Abdullah M. Al-Youbi, Abdulrahman O. Faidallah, Hassan M. Ng, Seik Weng Tiekink, Edward R. T. |
| author_sort | Asiri, Abdullah M. |
| collection | PubMed |
| description | In the title compound, C(23)H(15)N(3)O(2), significant deviations from planarity are evidenced in the values of the dihedral angles formed between the amino-benzene ring and the benzene rings of the 1,3-benzodioxole [65.38 (12)°] and 1,2-dihydronaphthalene [26.27 (14)°] residues; the dioxole ring has an envelope conformation with the methylene-C being the flap atom. The amino-H atoms form hydrogen bonds to one of the dioxole-O atoms and to one of the cyano-N atoms to generate a two-dimensional array with a zigzag topology that stacks along the ([Image: see text] 0 2) plane. |
| format | Online Article Text |
| id | pubmed-3200934 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-32009342011-11-06 3-Amino-1-(2H-1,3-benzodioxol-5-yl)-9,10-dihydrophenanthrene-2,4-dicarbonitrile Asiri, Abdullah M. Al-Youbi, Abdulrahman O. Faidallah, Hassan M. Ng, Seik Weng Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(23)H(15)N(3)O(2), significant deviations from planarity are evidenced in the values of the dihedral angles formed between the amino-benzene ring and the benzene rings of the 1,3-benzodioxole [65.38 (12)°] and 1,2-dihydronaphthalene [26.27 (14)°] residues; the dioxole ring has an envelope conformation with the methylene-C being the flap atom. The amino-H atoms form hydrogen bonds to one of the dioxole-O atoms and to one of the cyano-N atoms to generate a two-dimensional array with a zigzag topology that stacks along the ([Image: see text] 0 2) plane. International Union of Crystallography 2011-08-27 /pmc/articles/PMC3200934/ /pubmed/22059011 http://dx.doi.org/10.1107/S1600536811033563 Text en © Asiri et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Organic Papers Asiri, Abdullah M. Al-Youbi, Abdulrahman O. Faidallah, Hassan M. Ng, Seik Weng Tiekink, Edward R. T. 3-Amino-1-(2H-1,3-benzodioxol-5-yl)-9,10-dihydrophenanthrene-2,4-dicarbonitrile |
| title | 3-Amino-1-(2H-1,3-benzodioxol-5-yl)-9,10-dihydrophenanthrene-2,4-dicarbonitrile |
| title_full | 3-Amino-1-(2H-1,3-benzodioxol-5-yl)-9,10-dihydrophenanthrene-2,4-dicarbonitrile |
| title_fullStr | 3-Amino-1-(2H-1,3-benzodioxol-5-yl)-9,10-dihydrophenanthrene-2,4-dicarbonitrile |
| title_full_unstemmed | 3-Amino-1-(2H-1,3-benzodioxol-5-yl)-9,10-dihydrophenanthrene-2,4-dicarbonitrile |
| title_short | 3-Amino-1-(2H-1,3-benzodioxol-5-yl)-9,10-dihydrophenanthrene-2,4-dicarbonitrile |
| title_sort | 3-amino-1-(2h-1,3-benzodioxol-5-yl)-9,10-dihydrophenanthrene-2,4-dicarbonitrile |
| topic | Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200934/ https://www.ncbi.nlm.nih.gov/pubmed/22059011 http://dx.doi.org/10.1107/S1600536811033563 |
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