1(4),5(4)-Dichloro-3(2,7),7(2,7)-dinaphthal­ena-2,4,6,8-tetra­oxa-1(2,6),5(2,6)-di(1,3,5-triazina)octa­phane

In the macrocyclic title compound, C(26)H(12)Cl(2)N(6)O(4), an O-atom-bridged calix[2]naphthalene­[2]triazine synthesized using a one-pot approach from naphthalene-2,7-diol and cyanuric chloride, the two isolated naphthalene planes and the two triazine-2,6-di­oxy planes adopt a 1,3-alternate configu...

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Detalles Bibliográficos
Autores principales: Sang, Qiu-Guang, Yang, Jing-Kui
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200940/
https://www.ncbi.nlm.nih.gov/pubmed/22065129
http://dx.doi.org/10.1107/S160053681103460X
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author Sang, Qiu-Guang
Yang, Jing-Kui
author_facet Sang, Qiu-Guang
Yang, Jing-Kui
author_sort Sang, Qiu-Guang
collection PubMed
description In the macrocyclic title compound, C(26)H(12)Cl(2)N(6)O(4), an O-atom-bridged calix[2]naphthalene­[2]triazine synthesized using a one-pot approach from naphthalene-2,7-diol and cyanuric chloride, the two isolated naphthalene planes and the two triazine-2,6-di­oxy planes adopt a 1,3-alternate configuration, with a dihedral angle of 84.10 (8)° between the naphthalene rings and a dihedral angle of 39.02 (14)° between the triazine rings. In the crystal, weak inter­molecular π–π stacking inter­actions are found between face-to-face naphthalene rings [centroid–centroid distance = 3.662 (7) Å].
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spelling pubmed-32009402011-11-06 1(4),5(4)-Dichloro-3(2,7),7(2,7)-dinaphthal­ena-2,4,6,8-tetra­oxa-1(2,6),5(2,6)-di(1,3,5-triazina)octa­phane Sang, Qiu-Guang Yang, Jing-Kui Acta Crystallogr Sect E Struct Rep Online Organic Papers In the macrocyclic title compound, C(26)H(12)Cl(2)N(6)O(4), an O-atom-bridged calix[2]naphthalene­[2]triazine synthesized using a one-pot approach from naphthalene-2,7-diol and cyanuric chloride, the two isolated naphthalene planes and the two triazine-2,6-di­oxy planes adopt a 1,3-alternate configuration, with a dihedral angle of 84.10 (8)° between the naphthalene rings and a dihedral angle of 39.02 (14)° between the triazine rings. In the crystal, weak inter­molecular π–π stacking inter­actions are found between face-to-face naphthalene rings [centroid–centroid distance = 3.662 (7) Å]. International Union of Crystallography 2011-08-31 /pmc/articles/PMC3200940/ /pubmed/22065129 http://dx.doi.org/10.1107/S160053681103460X Text en © Sang and Yang 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Sang, Qiu-Guang
Yang, Jing-Kui
1(4),5(4)-Dichloro-3(2,7),7(2,7)-dinaphthal­ena-2,4,6,8-tetra­oxa-1(2,6),5(2,6)-di(1,3,5-triazina)octa­phane
title 1(4),5(4)-Dichloro-3(2,7),7(2,7)-dinaphthal­ena-2,4,6,8-tetra­oxa-1(2,6),5(2,6)-di(1,3,5-triazina)octa­phane
title_full 1(4),5(4)-Dichloro-3(2,7),7(2,7)-dinaphthal­ena-2,4,6,8-tetra­oxa-1(2,6),5(2,6)-di(1,3,5-triazina)octa­phane
title_fullStr 1(4),5(4)-Dichloro-3(2,7),7(2,7)-dinaphthal­ena-2,4,6,8-tetra­oxa-1(2,6),5(2,6)-di(1,3,5-triazina)octa­phane
title_full_unstemmed 1(4),5(4)-Dichloro-3(2,7),7(2,7)-dinaphthal­ena-2,4,6,8-tetra­oxa-1(2,6),5(2,6)-di(1,3,5-triazina)octa­phane
title_short 1(4),5(4)-Dichloro-3(2,7),7(2,7)-dinaphthal­ena-2,4,6,8-tetra­oxa-1(2,6),5(2,6)-di(1,3,5-triazina)octa­phane
title_sort 1(4),5(4)-dichloro-3(2,7),7(2,7)-dinaphthal­ena-2,4,6,8-tetra­oxa-1(2,6),5(2,6)-di(1,3,5-triazina)octa­phane
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200940/
https://www.ncbi.nlm.nih.gov/pubmed/22065129
http://dx.doi.org/10.1107/S160053681103460X
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AT yangjingkui 1454dichloro327727dinaphthalena2468tetraoxa126526di135triazinaoctaphane

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