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Diaqua­(5-carb­oxy­benzene-1,3-dicarboxyl­ato-κ(2) O (1),O (1′))(6,6′-dimethyl-2,2′-bipyridine-κ(2) N,N′)nickel(II) hepta­hydrate

In the title compound, [Ni(C(9)H(4)O(6))(C(12)H(12)N(2))(H(2)O)(2)]·7H(2)O, the Ni(II) atom is six-coordinated by two O atoms from a chelating carboxyl­ate group of a 5-carb­oxy­benzene-1,3-dicarboxyl­ate ligand, two O atoms of two water mol­ecules and two N atoms from a 6,6′-dimethyl-2,2′-bipyridin...

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Detalles Bibliográficos
Autores principales: Shan, Wen-Wen, Xiong, Han-Lin, Mei, Chong-Zhen
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200942/
https://www.ncbi.nlm.nih.gov/pubmed/22065470
http://dx.doi.org/10.1107/S1600536811032090
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author Shan, Wen-Wen
Xiong, Han-Lin
Mei, Chong-Zhen
author_facet Shan, Wen-Wen
Xiong, Han-Lin
Mei, Chong-Zhen
author_sort Shan, Wen-Wen
collection PubMed
description In the title compound, [Ni(C(9)H(4)O(6))(C(12)H(12)N(2))(H(2)O)(2)]·7H(2)O, the Ni(II) atom is six-coordinated by two O atoms from a chelating carboxyl­ate group of a 5-carb­oxy­benzene-1,3-dicarboxyl­ate ligand, two O atoms of two water mol­ecules and two N atoms from a 6,6′-dimethyl-2,2′-bipyridine ligand in a distorted octa­hedral geometry. The compound exhibits a three-dimensional supra­molecular structure composed of the complex mol­ecules and lattice water mol­ecules, which are linked together by inter­molecular O—H⋯O hydrogen bonds and partly overlapping π–π inter­actions between the pyridine and benzene rings [centroid–centroid distances = 3.922 (2) and 3.921 (2) Å]. One of the lattice water mol­ecules is disordered over two positions in an occupancy ratio of 0.521 (6):0.479 (6).
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spelling pubmed-32009422011-11-06 Diaqua­(5-carb­oxy­benzene-1,3-dicarboxyl­ato-κ(2) O (1),O (1′))(6,6′-dimethyl-2,2′-bipyridine-κ(2) N,N′)nickel(II) hepta­hydrate Shan, Wen-Wen Xiong, Han-Lin Mei, Chong-Zhen Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Ni(C(9)H(4)O(6))(C(12)H(12)N(2))(H(2)O)(2)]·7H(2)O, the Ni(II) atom is six-coordinated by two O atoms from a chelating carboxyl­ate group of a 5-carb­oxy­benzene-1,3-dicarboxyl­ate ligand, two O atoms of two water mol­ecules and two N atoms from a 6,6′-dimethyl-2,2′-bipyridine ligand in a distorted octa­hedral geometry. The compound exhibits a three-dimensional supra­molecular structure composed of the complex mol­ecules and lattice water mol­ecules, which are linked together by inter­molecular O—H⋯O hydrogen bonds and partly overlapping π–π inter­actions between the pyridine and benzene rings [centroid–centroid distances = 3.922 (2) and 3.921 (2) Å]. One of the lattice water mol­ecules is disordered over two positions in an occupancy ratio of 0.521 (6):0.479 (6). International Union of Crystallography 2011-08-17 /pmc/articles/PMC3200942/ /pubmed/22065470 http://dx.doi.org/10.1107/S1600536811032090 Text en © Shan et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Shan, Wen-Wen
Xiong, Han-Lin
Mei, Chong-Zhen
Diaqua­(5-carb­oxy­benzene-1,3-dicarboxyl­ato-κ(2) O (1),O (1′))(6,6′-dimethyl-2,2′-bipyridine-κ(2) N,N′)nickel(II) hepta­hydrate
title Diaqua­(5-carb­oxy­benzene-1,3-dicarboxyl­ato-κ(2) O (1),O (1′))(6,6′-dimethyl-2,2′-bipyridine-κ(2) N,N′)nickel(II) hepta­hydrate
title_full Diaqua­(5-carb­oxy­benzene-1,3-dicarboxyl­ato-κ(2) O (1),O (1′))(6,6′-dimethyl-2,2′-bipyridine-κ(2) N,N′)nickel(II) hepta­hydrate
title_fullStr Diaqua­(5-carb­oxy­benzene-1,3-dicarboxyl­ato-κ(2) O (1),O (1′))(6,6′-dimethyl-2,2′-bipyridine-κ(2) N,N′)nickel(II) hepta­hydrate
title_full_unstemmed Diaqua­(5-carb­oxy­benzene-1,3-dicarboxyl­ato-κ(2) O (1),O (1′))(6,6′-dimethyl-2,2′-bipyridine-κ(2) N,N′)nickel(II) hepta­hydrate
title_short Diaqua­(5-carb­oxy­benzene-1,3-dicarboxyl­ato-κ(2) O (1),O (1′))(6,6′-dimethyl-2,2′-bipyridine-κ(2) N,N′)nickel(II) hepta­hydrate
title_sort diaqua­(5-carb­oxy­benzene-1,3-dicarboxyl­ato-κ(2) o (1),o (1′))(6,6′-dimethyl-2,2′-bipyridine-κ(2) n,n′)nickel(ii) hepta­hydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200942/
https://www.ncbi.nlm.nih.gov/pubmed/22065470
http://dx.doi.org/10.1107/S1600536811032090
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AT meichongzhen diaqua5carboxybenzene13dicarboxylatok2o1o166dimethyl22bipyridinek2nnnickeliiheptahydrate