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Diaqua(5-carboxybenzene-1,3-dicarboxylato-κ(2) O (1),O (1′))(6,6′-dimethyl-2,2′-bipyridine-κ(2) N,N′)nickel(II) heptahydrate
In the title compound, [Ni(C(9)H(4)O(6))(C(12)H(12)N(2))(H(2)O)(2)]·7H(2)O, the Ni(II) atom is six-coordinated by two O atoms from a chelating carboxylate group of a 5-carboxybenzene-1,3-dicarboxylate ligand, two O atoms of two water molecules and two N atoms from a 6,6′-dimethyl-2,2′-bipyridin...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200942/ https://www.ncbi.nlm.nih.gov/pubmed/22065470 http://dx.doi.org/10.1107/S1600536811032090 |
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author | Shan, Wen-Wen Xiong, Han-Lin Mei, Chong-Zhen |
author_facet | Shan, Wen-Wen Xiong, Han-Lin Mei, Chong-Zhen |
author_sort | Shan, Wen-Wen |
collection | PubMed |
description | In the title compound, [Ni(C(9)H(4)O(6))(C(12)H(12)N(2))(H(2)O)(2)]·7H(2)O, the Ni(II) atom is six-coordinated by two O atoms from a chelating carboxylate group of a 5-carboxybenzene-1,3-dicarboxylate ligand, two O atoms of two water molecules and two N atoms from a 6,6′-dimethyl-2,2′-bipyridine ligand in a distorted octahedral geometry. The compound exhibits a three-dimensional supramolecular structure composed of the complex molecules and lattice water molecules, which are linked together by intermolecular O—H⋯O hydrogen bonds and partly overlapping π–π interactions between the pyridine and benzene rings [centroid–centroid distances = 3.922 (2) and 3.921 (2) Å]. One of the lattice water molecules is disordered over two positions in an occupancy ratio of 0.521 (6):0.479 (6). |
format | Online Article Text |
id | pubmed-3200942 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32009422011-11-06 Diaqua(5-carboxybenzene-1,3-dicarboxylato-κ(2) O (1),O (1′))(6,6′-dimethyl-2,2′-bipyridine-κ(2) N,N′)nickel(II) heptahydrate Shan, Wen-Wen Xiong, Han-Lin Mei, Chong-Zhen Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Ni(C(9)H(4)O(6))(C(12)H(12)N(2))(H(2)O)(2)]·7H(2)O, the Ni(II) atom is six-coordinated by two O atoms from a chelating carboxylate group of a 5-carboxybenzene-1,3-dicarboxylate ligand, two O atoms of two water molecules and two N atoms from a 6,6′-dimethyl-2,2′-bipyridine ligand in a distorted octahedral geometry. The compound exhibits a three-dimensional supramolecular structure composed of the complex molecules and lattice water molecules, which are linked together by intermolecular O—H⋯O hydrogen bonds and partly overlapping π–π interactions between the pyridine and benzene rings [centroid–centroid distances = 3.922 (2) and 3.921 (2) Å]. One of the lattice water molecules is disordered over two positions in an occupancy ratio of 0.521 (6):0.479 (6). International Union of Crystallography 2011-08-17 /pmc/articles/PMC3200942/ /pubmed/22065470 http://dx.doi.org/10.1107/S1600536811032090 Text en © Shan et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Shan, Wen-Wen Xiong, Han-Lin Mei, Chong-Zhen Diaqua(5-carboxybenzene-1,3-dicarboxylato-κ(2) O (1),O (1′))(6,6′-dimethyl-2,2′-bipyridine-κ(2) N,N′)nickel(II) heptahydrate |
title | Diaqua(5-carboxybenzene-1,3-dicarboxylato-κ(2)
O
(1),O
(1′))(6,6′-dimethyl-2,2′-bipyridine-κ(2)
N,N′)nickel(II) heptahydrate |
title_full | Diaqua(5-carboxybenzene-1,3-dicarboxylato-κ(2)
O
(1),O
(1′))(6,6′-dimethyl-2,2′-bipyridine-κ(2)
N,N′)nickel(II) heptahydrate |
title_fullStr | Diaqua(5-carboxybenzene-1,3-dicarboxylato-κ(2)
O
(1),O
(1′))(6,6′-dimethyl-2,2′-bipyridine-κ(2)
N,N′)nickel(II) heptahydrate |
title_full_unstemmed | Diaqua(5-carboxybenzene-1,3-dicarboxylato-κ(2)
O
(1),O
(1′))(6,6′-dimethyl-2,2′-bipyridine-κ(2)
N,N′)nickel(II) heptahydrate |
title_short | Diaqua(5-carboxybenzene-1,3-dicarboxylato-κ(2)
O
(1),O
(1′))(6,6′-dimethyl-2,2′-bipyridine-κ(2)
N,N′)nickel(II) heptahydrate |
title_sort | diaqua(5-carboxybenzene-1,3-dicarboxylato-κ(2)
o
(1),o
(1′))(6,6′-dimethyl-2,2′-bipyridine-κ(2)
n,n′)nickel(ii) heptahydrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200942/ https://www.ncbi.nlm.nih.gov/pubmed/22065470 http://dx.doi.org/10.1107/S1600536811032090 |
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