Cargando…
Propane-1,3-diaminium bis(pyridine-4-carboxylate) monohydrate
The asymmetric unit of the title compound, C(3)H(12)N(2) (2+)·2C(6)H(4)NO(2) (−)·H(2)O, consists of half of a doubly protonated propane-1,3-diammonium dication, a pyridine-4-carboxylate anion and half of a solvent water molecule; the dication and the solvent water are located on a twofold rotation...
Autores principales: | , , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200944/ https://www.ncbi.nlm.nih.gov/pubmed/22065654 http://dx.doi.org/10.1107/S1600536811033502 |
Sumario: | The asymmetric unit of the title compound, C(3)H(12)N(2) (2+)·2C(6)H(4)NO(2) (−)·H(2)O, consists of half of a doubly protonated propane-1,3-diammonium dication, a pyridine-4-carboxylate anion and half of a solvent water molecule; the dication and the solvent water are located on a twofold rotation axis which passes through the central C atom of the dication and the water O atom. The carboxylate group of the anion appears to be delocalized on the basis of the C—O bond lengths. In the crystal, the components are linked by intermolecular N—H⋯O, N—H⋯N and O—H⋯O hydrogen bonds. |
---|