8-Hy­droxy-2-methyl­quinolinium dichlorido(2-methyl­quinolin-8-olato-κ(2) N,O)zincate acetonitrile disolvate

The reaction of 2-methyl-8-hy­droxy­quinoline and zinc chloride in acetonitrile affords the title solvated salt, (C(10)H(10)NO)[Zn(C(10)H(8)NO)Cl(2)]·2CH(3)CN, in which the Zn(II) atom is coordinated by an­ N,O-chelating 2-methyl­quinolin-8-olate ligand and two chloride ligands in a distorted tetra­...

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Detalles Bibliográficos
Autores principales: Najafi, Ezzatollah, Amini, Mostafa M., Ng, Seik Weng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200945/
https://www.ncbi.nlm.nih.gov/pubmed/22058876
http://dx.doi.org/10.1107/S1600536811032338
Descripción
Sumario:The reaction of 2-methyl-8-hy­droxy­quinoline and zinc chloride in acetonitrile affords the title solvated salt, (C(10)H(10)NO)[Zn(C(10)H(8)NO)Cl(2)]·2CH(3)CN, in which the Zn(II) atom is coordinated by an­ N,O-chelating 2-methyl­quinolin-8-olate ligand and two chloride ligands in a distorted tetra­hedral geometry. The cation is linked to the heterocyclic anion by an O—H⋯O hydrogen bond and the quinolinium H atom forms a inter­molecular N—H⋯N hydrogen bond with one of the acetonitrile solvent mol­ecules.

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