8-Hy­droxy-2-methyl­quinolinium dichlorido(2-methyl­quinolin-8-olato-κ(2) N,O)zincate acetonitrile disolvate

The reaction of 2-methyl-8-hy­droxy­quinoline and zinc chloride in acetonitrile affords the title solvated salt, (C(10)H(10)NO)[Zn(C(10)H(8)NO)Cl(2)]·2CH(3)CN, in which the Zn(II) atom is coordinated by an­ N,O-chelating 2-methyl­quinolin-8-olate ligand and two chloride ligands in a distorted tetra­...

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Detalles Bibliográficos
Autores principales: Najafi, Ezzatollah, Amini, Mostafa M., Ng, Seik Weng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200945/
https://www.ncbi.nlm.nih.gov/pubmed/22058876
http://dx.doi.org/10.1107/S1600536811032338
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author Najafi, Ezzatollah
Amini, Mostafa M.
Ng, Seik Weng
author_facet Najafi, Ezzatollah
Amini, Mostafa M.
Ng, Seik Weng
author_sort Najafi, Ezzatollah
collection PubMed
description The reaction of 2-methyl-8-hy­droxy­quinoline and zinc chloride in acetonitrile affords the title solvated salt, (C(10)H(10)NO)[Zn(C(10)H(8)NO)Cl(2)]·2CH(3)CN, in which the Zn(II) atom is coordinated by an­ N,O-chelating 2-methyl­quinolin-8-olate ligand and two chloride ligands in a distorted tetra­hedral geometry. The cation is linked to the heterocyclic anion by an O—H⋯O hydrogen bond and the quinolinium H atom forms a inter­molecular N—H⋯N hydrogen bond with one of the acetonitrile solvent mol­ecules.
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spelling pubmed-32009452011-11-06 8-Hy­droxy-2-methyl­quinolinium dichlorido(2-methyl­quinolin-8-olato-κ(2) N,O)zincate acetonitrile disolvate Najafi, Ezzatollah Amini, Mostafa M. Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The reaction of 2-methyl-8-hy­droxy­quinoline and zinc chloride in acetonitrile affords the title solvated salt, (C(10)H(10)NO)[Zn(C(10)H(8)NO)Cl(2)]·2CH(3)CN, in which the Zn(II) atom is coordinated by an­ N,O-chelating 2-methyl­quinolin-8-olate ligand and two chloride ligands in a distorted tetra­hedral geometry. The cation is linked to the heterocyclic anion by an O—H⋯O hydrogen bond and the quinolinium H atom forms a inter­molecular N—H⋯N hydrogen bond with one of the acetonitrile solvent mol­ecules. International Union of Crystallography 2011-08-27 /pmc/articles/PMC3200945/ /pubmed/22058876 http://dx.doi.org/10.1107/S1600536811032338 Text en © Najafi et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Najafi, Ezzatollah
Amini, Mostafa M.
Ng, Seik Weng
8-Hy­droxy-2-methyl­quinolinium dichlorido(2-methyl­quinolin-8-olato-κ(2) N,O)zincate acetonitrile disolvate
title 8-Hy­droxy-2-methyl­quinolinium dichlorido(2-methyl­quinolin-8-olato-κ(2) N,O)zincate acetonitrile disolvate
title_full 8-Hy­droxy-2-methyl­quinolinium dichlorido(2-methyl­quinolin-8-olato-κ(2) N,O)zincate acetonitrile disolvate
title_fullStr 8-Hy­droxy-2-methyl­quinolinium dichlorido(2-methyl­quinolin-8-olato-κ(2) N,O)zincate acetonitrile disolvate
title_full_unstemmed 8-Hy­droxy-2-methyl­quinolinium dichlorido(2-methyl­quinolin-8-olato-κ(2) N,O)zincate acetonitrile disolvate
title_short 8-Hy­droxy-2-methyl­quinolinium dichlorido(2-methyl­quinolin-8-olato-κ(2) N,O)zincate acetonitrile disolvate
title_sort 8-hy­droxy-2-methyl­quinolinium dichlorido(2-methyl­quinolin-8-olato-κ(2) n,o)zincate acetonitrile disolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200945/
https://www.ncbi.nlm.nih.gov/pubmed/22058876
http://dx.doi.org/10.1107/S1600536811032338
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AT ngseikweng 8hydroxy2methylquinoliniumdichlorido2methylquinolin8olatok2nozincateacetonitriledisolvate

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