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Ethyl N-[4-(3-methyl-4,5-dihydro­benzo[g]indazol-1-yl)phenyl­sulfon­yl]thio­carbam­ate ethanol monosolvate

The title compound, C(21)H(20)N(3)O(3)S(2)·CH(3)CH(2)OH, comprises two independent organic mol­ecules and two ethanol solvent mol­ecules. The mol­ecules are related by pseudo-mirror symmetry. In both mol­ecules, the N-bound benzene ring is twisted out of the plane of the pyrazole ring [the dihedral...

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Detalles Bibliográficos
Autores principales: Asiri, Abdullah M., Al-Youbi, Abdulrahman O., Faidallah, Hassan M., Ng, Seik Weng, Tiekink, Edward R. T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200955/
https://www.ncbi.nlm.nih.gov/pubmed/22059018
http://dx.doi.org/10.1107/S1600536811034076
Descripción
Sumario:The title compound, C(21)H(20)N(3)O(3)S(2)·CH(3)CH(2)OH, comprises two independent organic mol­ecules and two ethanol solvent mol­ecules. The mol­ecules are related by pseudo-mirror symmetry. In both mol­ecules, the N-bound benzene ring is twisted out of the plane of the pyrazole ring [the dihedral angles are 51.4 (3) and 44.1 (3)°, respectively]. Similarly, the benzene ring of the 1,2-dihydro­naphthalene residue is inclined with respect to the five-membered ring [dihedral angles 18.3 (3) and 22.2 (3)°]. Overall, each mol­ecule has a flattened U shape. Dimeric aggregates mediated by O—H⋯N(pyrazole) and amide-N—H⋯O hydrogen bonds feature in the crystal packing, whereby the ethanol mol­ecules link the independent organic mol­ecules, leading to four-mol­ecule aggregates.