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Poly[[[μ(3)-5-(pyridine-4-carboxamido)isophthalato]{μ(3)-5-[(pyridin-1-ium-4-yl)carbonylamino]isophthalato}neodymium(III)] dihydrate]
In the title compound, {[Nd(C(14)H(9)N(2)O(5))(C(14)H(8)N(2)O(5))]·2H(2)O}(n), the Nd(III) atom is eight-coordinated as it is surrounded by eight carboxylate O atoms from six ligands in a distorted square-antiprismatic arrangement. The Nd(III) atoms are linked by HL (−) and L (2−) ligands [H(2) L...
Autor principal: | |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200962/ https://www.ncbi.nlm.nih.gov/pubmed/22058886 http://dx.doi.org/10.1107/S1600536811034532 |
Sumario: | In the title compound, {[Nd(C(14)H(9)N(2)O(5))(C(14)H(8)N(2)O(5))]·2H(2)O}(n), the Nd(III) atom is eight-coordinated as it is surrounded by eight carboxylate O atoms from six ligands in a distorted square-antiprismatic arrangement. The Nd(III) atoms are linked by HL (−) and L (2−) ligands [H(2) L is 5-(pyridine-4-carboxamido)isophthalic acid], forming a bilayer network. The layers are linked into a three-demensional network through N—H⋯O and O—H⋯O hydrogen bonds. |
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