Poly[[[μ(3)-5-(pyridine-4-carboxamido)­isophthalato]{μ(3)-5-[(pyridin-1-ium-4-yl)carbonyl­amino]­isophthalato}­neodymium(III)] dihydrate]

In the title compound, {[Nd(C(14)H(9)N(2)O(5))(C(14)H(8)N(2)O(5))]·2H(2)O}(n), the Nd(III) atom is eight-coordinated as it is surrounded by eight carboxyl­ate O atoms from six ligands in a distorted square-anti­prismatic arrangement. The Nd(III) atoms are linked by HL (−) and L (2−) ligands [H(2) L...

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Detalles Bibliográficos
Autor principal: Deng, Yi-Fang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200962/
https://www.ncbi.nlm.nih.gov/pubmed/22058886
http://dx.doi.org/10.1107/S1600536811034532
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author Deng, Yi-Fang
author_facet Deng, Yi-Fang
author_sort Deng, Yi-Fang
collection PubMed
description In the title compound, {[Nd(C(14)H(9)N(2)O(5))(C(14)H(8)N(2)O(5))]·2H(2)O}(n), the Nd(III) atom is eight-coordinated as it is surrounded by eight carboxyl­ate O atoms from six ligands in a distorted square-anti­prismatic arrangement. The Nd(III) atoms are linked by HL (−) and L (2−) ligands [H(2) L is 5-(pyridine-4-carboxamido)­isophthalic acid], forming a bilayer network. The layers are linked into a three-demensional network through N—H⋯O and O—H⋯O hydrogen bonds.
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spelling pubmed-32009622011-11-06 Poly[[[μ(3)-5-(pyridine-4-carboxamido)­isophthalato]{μ(3)-5-[(pyridin-1-ium-4-yl)carbonyl­amino]­isophthalato}­neodymium(III)] dihydrate] Deng, Yi-Fang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, {[Nd(C(14)H(9)N(2)O(5))(C(14)H(8)N(2)O(5))]·2H(2)O}(n), the Nd(III) atom is eight-coordinated as it is surrounded by eight carboxyl­ate O atoms from six ligands in a distorted square-anti­prismatic arrangement. The Nd(III) atoms are linked by HL (−) and L (2−) ligands [H(2) L is 5-(pyridine-4-carboxamido)­isophthalic acid], forming a bilayer network. The layers are linked into a three-demensional network through N—H⋯O and O—H⋯O hydrogen bonds. International Union of Crystallography 2011-08-27 /pmc/articles/PMC3200962/ /pubmed/22058886 http://dx.doi.org/10.1107/S1600536811034532 Text en © Yi-Fang Deng 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Deng, Yi-Fang
Poly[[[μ(3)-5-(pyridine-4-carboxamido)­isophthalato]{μ(3)-5-[(pyridin-1-ium-4-yl)carbonyl­amino]­isophthalato}­neodymium(III)] dihydrate]
title Poly[[[μ(3)-5-(pyridine-4-carboxamido)­isophthalato]{μ(3)-5-[(pyridin-1-ium-4-yl)carbonyl­amino]­isophthalato}­neodymium(III)] dihydrate]
title_full Poly[[[μ(3)-5-(pyridine-4-carboxamido)­isophthalato]{μ(3)-5-[(pyridin-1-ium-4-yl)carbonyl­amino]­isophthalato}­neodymium(III)] dihydrate]
title_fullStr Poly[[[μ(3)-5-(pyridine-4-carboxamido)­isophthalato]{μ(3)-5-[(pyridin-1-ium-4-yl)carbonyl­amino]­isophthalato}­neodymium(III)] dihydrate]
title_full_unstemmed Poly[[[μ(3)-5-(pyridine-4-carboxamido)­isophthalato]{μ(3)-5-[(pyridin-1-ium-4-yl)carbonyl­amino]­isophthalato}­neodymium(III)] dihydrate]
title_short Poly[[[μ(3)-5-(pyridine-4-carboxamido)­isophthalato]{μ(3)-5-[(pyridin-1-ium-4-yl)carbonyl­amino]­isophthalato}­neodymium(III)] dihydrate]
title_sort poly[[[μ(3)-5-(pyridine-4-carboxamido)­isophthalato]{μ(3)-5-[(pyridin-1-ium-4-yl)carbonyl­amino]­isophthalato}­neodymium(iii)] dihydrate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200962/
https://www.ncbi.nlm.nih.gov/pubmed/22058886
http://dx.doi.org/10.1107/S1600536811034532
work_keys_str_mv AT dengyifang polym35pyridine4carboxamidoisophthalatom35pyridin1ium4ylcarbonylaminoisophthalatoneodymiumiiidihydrate

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