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Tetraaquabis(2-methyl-1H-benzimidazolium-1,3-diacetato-κO)cobalt(II) tetrahydrate
In the title compound, [Co(C(12)H(11)N(2)O(4))(2)(H(2)O)(4)]·4H(2)O, the Co(II) atom lies on an inversion center and is octahedrally coordinated by six O atoms from four water molecules and two monodentate zwitterionic 2-methylbenzimidazolium-1,3-diacetate ligands. An intramolecular O—H⋯O hydrog...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2011
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200967/ https://www.ncbi.nlm.nih.gov/pubmed/22064811 http://dx.doi.org/10.1107/S1600536811029059 |
| Sumario: | In the title compound, [Co(C(12)H(11)N(2)O(4))(2)(H(2)O)(4)]·4H(2)O, the Co(II) atom lies on an inversion center and is octahedrally coordinated by six O atoms from four water molecules and two monodentate zwitterionic 2-methylbenzimidazolium-1,3-diacetate ligands. An intramolecular O—H⋯O hydrogen bond occurs. In the crystal, intermolecular O—H⋯O hydrogen bonds link the molecules into a three-dimensional network. π–π interactions between the imidazole and benzene rings [centroid–centroid distance = 3.9031 (17) Å] consolidate the crystal packing. |
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