Tetra­aqua­bis­(2-methyl-1H-benzimidazolium-1,3-diacetato-κO)cobalt(II) tetra­hydrate

In the title compound, [Co(C(12)H(11)N(2)O(4))(2)(H(2)O)(4)]·4H(2)O, the Co(II) atom lies on an inversion center and is octa­hedrally coordinated by six O atoms from four water mol­ecules and two monodentate zwitterionic 2-methyl­benzimidazolium-1,3-diacetate ligands. An intra­molecular O—H⋯O hydrog...

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Detalles Bibliográficos
Autores principales: Feng, Xiu-Ling, Zhang, Yu-Ping
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200967/
https://www.ncbi.nlm.nih.gov/pubmed/22064811
http://dx.doi.org/10.1107/S1600536811029059
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author Feng, Xiu-Ling
Zhang, Yu-Ping
author_facet Feng, Xiu-Ling
Zhang, Yu-Ping
author_sort Feng, Xiu-Ling
collection PubMed
description In the title compound, [Co(C(12)H(11)N(2)O(4))(2)(H(2)O)(4)]·4H(2)O, the Co(II) atom lies on an inversion center and is octa­hedrally coordinated by six O atoms from four water mol­ecules and two monodentate zwitterionic 2-methyl­benzimidazolium-1,3-diacetate ligands. An intra­molecular O—H⋯O hydrogen bond occurs. In the crystal, inter­molecular O—H⋯O hydrogen bonds link the mol­ecules into a three-dimensional network. π–π inter­actions between the imidazole and benzene rings [centroid–centroid distance = 3.9031 (17) Å] consolidate the crystal packing.
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spelling pubmed-32009672011-11-06 Tetra­aqua­bis­(2-methyl-1H-benzimidazolium-1,3-diacetato-κO)cobalt(II) tetra­hydrate Feng, Xiu-Ling Zhang, Yu-Ping Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Co(C(12)H(11)N(2)O(4))(2)(H(2)O)(4)]·4H(2)O, the Co(II) atom lies on an inversion center and is octa­hedrally coordinated by six O atoms from four water mol­ecules and two monodentate zwitterionic 2-methyl­benzimidazolium-1,3-diacetate ligands. An intra­molecular O—H⋯O hydrogen bond occurs. In the crystal, inter­molecular O—H⋯O hydrogen bonds link the mol­ecules into a three-dimensional network. π–π inter­actions between the imidazole and benzene rings [centroid–centroid distance = 3.9031 (17) Å] consolidate the crystal packing. International Union of Crystallography 2011-08-02 /pmc/articles/PMC3200967/ /pubmed/22064811 http://dx.doi.org/10.1107/S1600536811029059 Text en © Feng and Zhang 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Feng, Xiu-Ling
Zhang, Yu-Ping
Tetra­aqua­bis­(2-methyl-1H-benzimidazolium-1,3-diacetato-κO)cobalt(II) tetra­hydrate
title Tetra­aqua­bis­(2-methyl-1H-benzimidazolium-1,3-diacetato-κO)cobalt(II) tetra­hydrate
title_full Tetra­aqua­bis­(2-methyl-1H-benzimidazolium-1,3-diacetato-κO)cobalt(II) tetra­hydrate
title_fullStr Tetra­aqua­bis­(2-methyl-1H-benzimidazolium-1,3-diacetato-κO)cobalt(II) tetra­hydrate
title_full_unstemmed Tetra­aqua­bis­(2-methyl-1H-benzimidazolium-1,3-diacetato-κO)cobalt(II) tetra­hydrate
title_short Tetra­aqua­bis­(2-methyl-1H-benzimidazolium-1,3-diacetato-κO)cobalt(II) tetra­hydrate
title_sort tetra­aqua­bis­(2-methyl-1h-benzimidazolium-1,3-diacetato-κo)cobalt(ii) tetra­hydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200967/
https://www.ncbi.nlm.nih.gov/pubmed/22064811
http://dx.doi.org/10.1107/S1600536811029059
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