(μ-Formato-κ (2) O:O′)bis­[dicarbon­yl(η (5)-cyclo­penta­dien­yl)iron(II)] tetra­fluoridoborate

In the structure of the title compound [Fe(2)(C(5)H(5))(2)(CHO(2))(CO)(4)]BF(4), each Fe(II) atom is coordinated in a pseudo-octa­hedral three-legged piano-stool fashion. The cyclo­penta­dienyl ligand occupies three fac coordination sites while the two carbonyl ligands and formate O atom occupy the...

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Detalles Bibliográficos
Autores principales: M’thiruaine, Cyprian M., Friedrich, Holger B., Changamu, Evans O., Omondi, Bernard
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200969/
https://www.ncbi.nlm.nih.gov/pubmed/22058865
http://dx.doi.org/10.1107/S1600536811032764
Descripción
Sumario:In the structure of the title compound [Fe(2)(C(5)H(5))(2)(CHO(2))(CO)(4)]BF(4), each Fe(II) atom is coordinated in a pseudo-octa­hedral three-legged piano-stool fashion. The cyclo­penta­dienyl ligand occupies three fac coordination sites while the two carbonyl ligands and formate O atom occupy the remaining three sites.

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