catena-Poly[[aqua­[1,4-bis­(1H-imidazol-4-yl)benzene]cadmium]-μ(3)-5-methyl­isophthalato]

In the title coordination polymer, [Cd(C(9)H(6)O(4))(C(12)H(10)N(4))(H(2)O)](n), the Cd(II) atom has a NO(6) donor set and is coord­inated by five carboxyl­ate O atoms from three different 5-methyl-1,3-phenyl­enediacetate (pda(2−)) anions, one O atom from a water mol­ecule and one N atom from a 1,4-...

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Detalles Bibliográficos
Autores principales: Yang, Sen-Lin, Wang, De-Hai, Chen, Shui-Sheng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200974/
https://www.ncbi.nlm.nih.gov/pubmed/22065019
http://dx.doi.org/10.1107/S1600536811030509
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author Yang, Sen-Lin
Wang, De-Hai
Chen, Shui-Sheng
author_facet Yang, Sen-Lin
Wang, De-Hai
Chen, Shui-Sheng
author_sort Yang, Sen-Lin
collection PubMed
description In the title coordination polymer, [Cd(C(9)H(6)O(4))(C(12)H(10)N(4))(H(2)O)](n), the Cd(II) atom has a NO(6) donor set and is coord­inated by five carboxyl­ate O atoms from three different 5-methyl-1,3-phenyl­enediacetate (pda(2−)) anions, one O atom from a water mol­ecule and one N atom from a 1,4-bis­(1H-imidazol-4-yl)benzene (L) ligand, displaying a highly distorted penta­gonal–bipyramidal geometry. Each pda(2−) anion acts as a μ(3)-bridge, linking Cd(II) atoms to form one-dimensional slabs extending parallel to [010]. In the crystal, adjacent mol­ecules are linked through N—H⋯N and N—H⋯O hydrogen bonds into a three-dimensional network.
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spelling pubmed-32009742011-11-06 catena-Poly[[aqua­[1,4-bis­(1H-imidazol-4-yl)benzene]cadmium]-μ(3)-5-methyl­isophthalato] Yang, Sen-Lin Wang, De-Hai Chen, Shui-Sheng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title coordination polymer, [Cd(C(9)H(6)O(4))(C(12)H(10)N(4))(H(2)O)](n), the Cd(II) atom has a NO(6) donor set and is coord­inated by five carboxyl­ate O atoms from three different 5-methyl-1,3-phenyl­enediacetate (pda(2−)) anions, one O atom from a water mol­ecule and one N atom from a 1,4-bis­(1H-imidazol-4-yl)benzene (L) ligand, displaying a highly distorted penta­gonal–bipyramidal geometry. Each pda(2−) anion acts as a μ(3)-bridge, linking Cd(II) atoms to form one-dimensional slabs extending parallel to [010]. In the crystal, adjacent mol­ecules are linked through N—H⋯N and N—H⋯O hydrogen bonds into a three-dimensional network. International Union of Crystallography 2011-08-02 /pmc/articles/PMC3200974/ /pubmed/22065019 http://dx.doi.org/10.1107/S1600536811030509 Text en © Yang et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Yang, Sen-Lin
Wang, De-Hai
Chen, Shui-Sheng
catena-Poly[[aqua­[1,4-bis­(1H-imidazol-4-yl)benzene]cadmium]-μ(3)-5-methyl­isophthalato]
title catena-Poly[[aqua­[1,4-bis­(1H-imidazol-4-yl)benzene]cadmium]-μ(3)-5-methyl­isophthalato]
title_full catena-Poly[[aqua­[1,4-bis­(1H-imidazol-4-yl)benzene]cadmium]-μ(3)-5-methyl­isophthalato]
title_fullStr catena-Poly[[aqua­[1,4-bis­(1H-imidazol-4-yl)benzene]cadmium]-μ(3)-5-methyl­isophthalato]
title_full_unstemmed catena-Poly[[aqua­[1,4-bis­(1H-imidazol-4-yl)benzene]cadmium]-μ(3)-5-methyl­isophthalato]
title_short catena-Poly[[aqua­[1,4-bis­(1H-imidazol-4-yl)benzene]cadmium]-μ(3)-5-methyl­isophthalato]
title_sort catena-poly[[aqua­[1,4-bis­(1h-imidazol-4-yl)benzene]cadmium]-μ(3)-5-methyl­isophthalato]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200974/
https://www.ncbi.nlm.nih.gov/pubmed/22065019
http://dx.doi.org/10.1107/S1600536811030509
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