Bis(4-amino­benzoato)-κ(2) O,O′;κO-(2,2′-bipyridine-κ(2) N,N′)zinc

In the title complex, [Zn(C(7)H(6)NO(2))(2)(C(10)H(8)N(2))], the Zn(II) cation is coordinated by two amino­benzoate anions and one 2,2′-bipyridine ligand in a distorted trigonal–bipyramidal geometry. The carboxyl­ate group of one aminobenzoate anion coordinates to the Zn(II) cation in a monodentate...

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Detalles Bibliográficos
Autores principales: Huang, Miao-Ling, Wang, Ling-Ling
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201216/
https://www.ncbi.nlm.nih.gov/pubmed/22058723
http://dx.doi.org/10.1107/S1600536811039389
Descripción
Sumario:In the title complex, [Zn(C(7)H(6)NO(2))(2)(C(10)H(8)N(2))], the Zn(II) cation is coordinated by two amino­benzoate anions and one 2,2′-bipyridine ligand in a distorted trigonal–bipyramidal geometry. The carboxyl­ate group of one aminobenzoate anion coordinates to the Zn(II) cation in a monodentate manner, whereas the carboxyl­ate group of the other amino­benzoate anion chelates the Zn cation with different Zn—O bond lengths. Inter­molecular N—H⋯N and N—H⋯O hydrogen bonding is present in the crystal structure.

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