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Bis(4-aminobenzoato)-κ(2) O,O′;κO-(2,2′-bipyridine-κ(2) N,N′)zinc
In the title complex, [Zn(C(7)H(6)NO(2))(2)(C(10)H(8)N(2))], the Zn(II) cation is coordinated by two aminobenzoate anions and one 2,2′-bipyridine ligand in a distorted trigonal–bipyramidal geometry. The carboxylate group of one aminobenzoate anion coordinates to the Zn(II) cation in a monodentate...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2011
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201216/ https://www.ncbi.nlm.nih.gov/pubmed/22058723 http://dx.doi.org/10.1107/S1600536811039389 |
| _version_ | 1782214823938883584 |
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| author | Huang, Miao-Ling Wang, Ling-Ling |
| author_facet | Huang, Miao-Ling Wang, Ling-Ling |
| author_sort | Huang, Miao-Ling |
| collection | PubMed |
| description | In the title complex, [Zn(C(7)H(6)NO(2))(2)(C(10)H(8)N(2))], the Zn(II) cation is coordinated by two aminobenzoate anions and one 2,2′-bipyridine ligand in a distorted trigonal–bipyramidal geometry. The carboxylate group of one aminobenzoate anion coordinates to the Zn(II) cation in a monodentate manner, whereas the carboxylate group of the other aminobenzoate anion chelates the Zn cation with different Zn—O bond lengths. Intermolecular N—H⋯N and N—H⋯O hydrogen bonding is present in the crystal structure. |
| format | Online Article Text |
| id | pubmed-3201216 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-32012162011-11-06 Bis(4-aminobenzoato)-κ(2) O,O′;κO-(2,2′-bipyridine-κ(2) N,N′)zinc Huang, Miao-Ling Wang, Ling-Ling Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Zn(C(7)H(6)NO(2))(2)(C(10)H(8)N(2))], the Zn(II) cation is coordinated by two aminobenzoate anions and one 2,2′-bipyridine ligand in a distorted trigonal–bipyramidal geometry. The carboxylate group of one aminobenzoate anion coordinates to the Zn(II) cation in a monodentate manner, whereas the carboxylate group of the other aminobenzoate anion chelates the Zn cation with different Zn—O bond lengths. Intermolecular N—H⋯N and N—H⋯O hydrogen bonding is present in the crystal structure. International Union of Crystallography 2011-09-30 /pmc/articles/PMC3201216/ /pubmed/22058723 http://dx.doi.org/10.1107/S1600536811039389 Text en © Huang and Wang 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Huang, Miao-Ling Wang, Ling-Ling Bis(4-aminobenzoato)-κ(2) O,O′;κO-(2,2′-bipyridine-κ(2) N,N′)zinc |
| title | Bis(4-aminobenzoato)-κ(2)
O,O′;κO-(2,2′-bipyridine-κ(2)
N,N′)zinc |
| title_full | Bis(4-aminobenzoato)-κ(2)
O,O′;κO-(2,2′-bipyridine-κ(2)
N,N′)zinc |
| title_fullStr | Bis(4-aminobenzoato)-κ(2)
O,O′;κO-(2,2′-bipyridine-κ(2)
N,N′)zinc |
| title_full_unstemmed | Bis(4-aminobenzoato)-κ(2)
O,O′;κO-(2,2′-bipyridine-κ(2)
N,N′)zinc |
| title_short | Bis(4-aminobenzoato)-κ(2)
O,O′;κO-(2,2′-bipyridine-κ(2)
N,N′)zinc |
| title_sort | bis(4-aminobenzoato)-κ(2)
o,o′;κo-(2,2′-bipyridine-κ(2)
n,n′)zinc |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201216/ https://www.ncbi.nlm.nih.gov/pubmed/22058723 http://dx.doi.org/10.1107/S1600536811039389 |
| work_keys_str_mv | AT huangmiaoling bis4aminobenzoatok2ooko22bipyridinek2nnzinc AT wanglingling bis4aminobenzoatok2ooko22bipyridinek2nnzinc |