2-Amino-4,6-dimethyl­pyridinium chloride dihydrate

In the title hydrated mol­ecular salt, C(7)H(11)N(2) (+)·Cl(−)·2H(2)O, the pyridine N atom of the 2-amino-4,6-dimethyl­pyridine mol­ecule is protonated. The cation is essentially planar, with a maximum deviation of 0.006 (2) Å. In the crystal, the components are linked by N—H⋯O, N—H⋯Cl and O—H⋯Cl hy...

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Autores principales: Al-Dajani, Mohammad T. M., Talaat, Jamal, Salhin, Abdusalam, Hemamalini, Madhukar, Fun, Hoong-Kun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201217/
https://www.ncbi.nlm.nih.gov/pubmed/22058738
http://dx.doi.org/10.1107/S1600536811035100
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author Al-Dajani, Mohammad T. M.
Talaat, Jamal
Salhin, Abdusalam
Hemamalini, Madhukar
Fun, Hoong-Kun
author_facet Al-Dajani, Mohammad T. M.
Talaat, Jamal
Salhin, Abdusalam
Hemamalini, Madhukar
Fun, Hoong-Kun
author_sort Al-Dajani, Mohammad T. M.
collection PubMed
description In the title hydrated mol­ecular salt, C(7)H(11)N(2) (+)·Cl(−)·2H(2)O, the pyridine N atom of the 2-amino-4,6-dimethyl­pyridine mol­ecule is protonated. The cation is essentially planar, with a maximum deviation of 0.006 (2) Å. In the crystal, the components are linked by N—H⋯O, N—H⋯Cl and O—H⋯Cl hydrogen bonds, thereby forming sheets lying parallel to (100). The crystal structure is further stabilized by aromatic π–π stacking inter­actions between the pyridinium rings [centroid–centroid distance = 3.4789 (9) Å].
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spelling pubmed-32012172011-11-06 2-Amino-4,6-dimethyl­pyridinium chloride dihydrate Al-Dajani, Mohammad T. M. Talaat, Jamal Salhin, Abdusalam Hemamalini, Madhukar Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title hydrated mol­ecular salt, C(7)H(11)N(2) (+)·Cl(−)·2H(2)O, the pyridine N atom of the 2-amino-4,6-dimethyl­pyridine mol­ecule is protonated. The cation is essentially planar, with a maximum deviation of 0.006 (2) Å. In the crystal, the components are linked by N—H⋯O, N—H⋯Cl and O—H⋯Cl hydrogen bonds, thereby forming sheets lying parallel to (100). The crystal structure is further stabilized by aromatic π–π stacking inter­actions between the pyridinium rings [centroid–centroid distance = 3.4789 (9) Å]. International Union of Crystallography 2011-09-14 /pmc/articles/PMC3201217/ /pubmed/22058738 http://dx.doi.org/10.1107/S1600536811035100 Text en © Al-Dajani et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Al-Dajani, Mohammad T. M.
Talaat, Jamal
Salhin, Abdusalam
Hemamalini, Madhukar
Fun, Hoong-Kun
2-Amino-4,6-dimethyl­pyridinium chloride dihydrate
title 2-Amino-4,6-dimethyl­pyridinium chloride dihydrate
title_full 2-Amino-4,6-dimethyl­pyridinium chloride dihydrate
title_fullStr 2-Amino-4,6-dimethyl­pyridinium chloride dihydrate
title_full_unstemmed 2-Amino-4,6-dimethyl­pyridinium chloride dihydrate
title_short 2-Amino-4,6-dimethyl­pyridinium chloride dihydrate
title_sort 2-amino-4,6-dimethyl­pyridinium chloride dihydrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201217/
https://www.ncbi.nlm.nih.gov/pubmed/22058738
http://dx.doi.org/10.1107/S1600536811035100
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AT salhinabdusalam 2amino46dimethylpyridiniumchloridedihydrate
AT hemamalinimadhukar 2amino46dimethylpyridiniumchloridedihydrate
AT funhoongkun 2amino46dimethylpyridiniumchloridedihydrate

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