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catena-Poly[[triaquanickel(II)]-μ-5-carboxybenzene-1,3-dicarboxylato-κ(2) O (1):O (3)]
In the title compound, [Ni(C(9)H(4)O(6))(H(2)O)(3)](n), the Ni(II) ion has a distorted NiO(5) square-pyramidal geometry, the maximum deviation from the least-squares plane formed by the basal atoms being 0.9351 (13) Å. The basal plane is formed by two O atoms from carboxylate residues of the 5-carb...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201226/ https://www.ncbi.nlm.nih.gov/pubmed/22058684 http://dx.doi.org/10.1107/S1600536811035227 |
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author | Yao, Xing-Jun Yuan, Qian |
author_facet | Yao, Xing-Jun Yuan, Qian |
author_sort | Yao, Xing-Jun |
collection | PubMed |
description | In the title compound, [Ni(C(9)H(4)O(6))(H(2)O)(3)](n), the Ni(II) ion has a distorted NiO(5) square-pyramidal geometry, the maximum deviation from the least-squares plane formed by the basal atoms being 0.9351 (13) Å. The basal plane is formed by two O atoms from carboxylate residues of the 5-carboxybenzene-1,3-dicarboxylate ligand and by two O atoms from water molecules. The O atom of the third water molecule is axially positioned, 1.7890 (19) Å perpendicular to the basal plane. The 5-carboxybenzene-1,3-dicarboxylate ligand bridges the metal atoms, forming a polymeric chain along the b axis. O—H⋯O hydrogen bonds between the water molecules and carboxylate groups stabilize the crystal structure. |
format | Online Article Text |
id | pubmed-3201226 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32012262011-11-06 catena-Poly[[triaquanickel(II)]-μ-5-carboxybenzene-1,3-dicarboxylato-κ(2) O (1):O (3)] Yao, Xing-Jun Yuan, Qian Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Ni(C(9)H(4)O(6))(H(2)O)(3)](n), the Ni(II) ion has a distorted NiO(5) square-pyramidal geometry, the maximum deviation from the least-squares plane formed by the basal atoms being 0.9351 (13) Å. The basal plane is formed by two O atoms from carboxylate residues of the 5-carboxybenzene-1,3-dicarboxylate ligand and by two O atoms from water molecules. The O atom of the third water molecule is axially positioned, 1.7890 (19) Å perpendicular to the basal plane. The 5-carboxybenzene-1,3-dicarboxylate ligand bridges the metal atoms, forming a polymeric chain along the b axis. O—H⋯O hydrogen bonds between the water molecules and carboxylate groups stabilize the crystal structure. International Union of Crystallography 2011-09-14 /pmc/articles/PMC3201226/ /pubmed/22058684 http://dx.doi.org/10.1107/S1600536811035227 Text en © Yao and Yuan 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Yao, Xing-Jun Yuan, Qian catena-Poly[[triaquanickel(II)]-μ-5-carboxybenzene-1,3-dicarboxylato-κ(2) O (1):O (3)] |
title |
catena-Poly[[triaquanickel(II)]-μ-5-carboxybenzene-1,3-dicarboxylato-κ(2)
O
(1):O
(3)] |
title_full |
catena-Poly[[triaquanickel(II)]-μ-5-carboxybenzene-1,3-dicarboxylato-κ(2)
O
(1):O
(3)] |
title_fullStr |
catena-Poly[[triaquanickel(II)]-μ-5-carboxybenzene-1,3-dicarboxylato-κ(2)
O
(1):O
(3)] |
title_full_unstemmed |
catena-Poly[[triaquanickel(II)]-μ-5-carboxybenzene-1,3-dicarboxylato-κ(2)
O
(1):O
(3)] |
title_short |
catena-Poly[[triaquanickel(II)]-μ-5-carboxybenzene-1,3-dicarboxylato-κ(2)
O
(1):O
(3)] |
title_sort | catena-poly[[triaquanickel(ii)]-μ-5-carboxybenzene-1,3-dicarboxylato-κ(2)
o
(1):o
(3)] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201226/ https://www.ncbi.nlm.nih.gov/pubmed/22058684 http://dx.doi.org/10.1107/S1600536811035227 |
work_keys_str_mv | AT yaoxingjun catenapolytriaquanickeliim5carboxybenzene13dicarboxylatok2o1o3 AT yuanqian catenapolytriaquanickeliim5carboxybenzene13dicarboxylatok2o1o3 |