[(E)-10-(2,6-Dimethyl­phenyl­imino)-9-methyl-9,10-dihydro­phenanthren-9-olato]penta­methyl­dialuminum(III)

The two Al atoms in the title compound, [Al(2)(CH(3))(5)(C(23)H(20)NO)], are four-coordinated in a distorted tetra­hedral environment. The coordination of one Al atom includes three methyl-C atoms and the O atom from the ligand, whereas the second Al atom is surrounded by the O atom and one N atom f...

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Detalles Bibliográficos
Autores principales: Gao, Bo, Su, Qing, Gao, Wei, Mu, Ying
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201228/
https://www.ncbi.nlm.nih.gov/pubmed/22065706
http://dx.doi.org/10.1107/S1600536811036312
Descripción
Sumario:The two Al atoms in the title compound, [Al(2)(CH(3))(5)(C(23)H(20)NO)], are four-coordinated in a distorted tetra­hedral environment. The coordination of one Al atom includes three methyl-C atoms and the O atom from the ligand, whereas the second Al atom is surrounded by the O atom and one N atom from the ligand as well as by two methyl-C atoms. In the ligand, the dihedral angle between the two phenyl rings in the 9,10-dihydro­phenanthren unit is 20.64 (12)°.

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