[(E)-10-(2,6-Dimethyl­phenyl­imino)-9-methyl-9,10-dihydro­phenanthren-9-olato]penta­methyl­dialuminum(III)

The two Al atoms in the title compound, [Al(2)(CH(3))(5)(C(23)H(20)NO)], are four-coordinated in a distorted tetra­hedral environment. The coordination of one Al atom includes three methyl-C atoms and the O atom from the ligand, whereas the second Al atom is surrounded by the O atom and one N atom f...

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Detalles Bibliográficos
Autores principales: Gao, Bo, Su, Qing, Gao, Wei, Mu, Ying
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201228/
https://www.ncbi.nlm.nih.gov/pubmed/22065706
http://dx.doi.org/10.1107/S1600536811036312
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author Gao, Bo
Su, Qing
Gao, Wei
Mu, Ying
author_facet Gao, Bo
Su, Qing
Gao, Wei
Mu, Ying
author_sort Gao, Bo
collection PubMed
description The two Al atoms in the title compound, [Al(2)(CH(3))(5)(C(23)H(20)NO)], are four-coordinated in a distorted tetra­hedral environment. The coordination of one Al atom includes three methyl-C atoms and the O atom from the ligand, whereas the second Al atom is surrounded by the O atom and one N atom from the ligand as well as by two methyl-C atoms. In the ligand, the dihedral angle between the two phenyl rings in the 9,10-dihydro­phenanthren unit is 20.64 (12)°.
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spelling pubmed-32012282011-11-06 [(E)-10-(2,6-Dimethyl­phenyl­imino)-9-methyl-9,10-dihydro­phenanthren-9-olato]penta­methyl­dialuminum(III) Gao, Bo Su, Qing Gao, Wei Mu, Ying Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The two Al atoms in the title compound, [Al(2)(CH(3))(5)(C(23)H(20)NO)], are four-coordinated in a distorted tetra­hedral environment. The coordination of one Al atom includes three methyl-C atoms and the O atom from the ligand, whereas the second Al atom is surrounded by the O atom and one N atom from the ligand as well as by two methyl-C atoms. In the ligand, the dihedral angle between the two phenyl rings in the 9,10-dihydro­phenanthren unit is 20.64 (12)°. International Union of Crystallography 2011-09-14 /pmc/articles/PMC3201228/ /pubmed/22065706 http://dx.doi.org/10.1107/S1600536811036312 Text en © Gao et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Gao, Bo
Su, Qing
Gao, Wei
Mu, Ying
[(E)-10-(2,6-Dimethyl­phenyl­imino)-9-methyl-9,10-dihydro­phenanthren-9-olato]penta­methyl­dialuminum(III)
title [(E)-10-(2,6-Dimethyl­phenyl­imino)-9-methyl-9,10-dihydro­phenanthren-9-olato]penta­methyl­dialuminum(III)
title_full [(E)-10-(2,6-Dimethyl­phenyl­imino)-9-methyl-9,10-dihydro­phenanthren-9-olato]penta­methyl­dialuminum(III)
title_fullStr [(E)-10-(2,6-Dimethyl­phenyl­imino)-9-methyl-9,10-dihydro­phenanthren-9-olato]penta­methyl­dialuminum(III)
title_full_unstemmed [(E)-10-(2,6-Dimethyl­phenyl­imino)-9-methyl-9,10-dihydro­phenanthren-9-olato]penta­methyl­dialuminum(III)
title_short [(E)-10-(2,6-Dimethyl­phenyl­imino)-9-methyl-9,10-dihydro­phenanthren-9-olato]penta­methyl­dialuminum(III)
title_sort [(e)-10-(2,6-dimethyl­phenyl­imino)-9-methyl-9,10-dihydro­phenanthren-9-olato]penta­methyl­dialuminum(iii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201228/
https://www.ncbi.nlm.nih.gov/pubmed/22065706
http://dx.doi.org/10.1107/S1600536811036312
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