Tri-μ-chlorido-bis­[(η(6)-hexa­methyl­benzene)­ruthenium(II)] tetra­chlorido­ferrate(III)

The mol­ecular geometry of the complex cation in the title structure, [(μ-Cl)(3){Ru(II)(η(6)-C(6)Me(6))}(2)][Fe(III)Cl(4)], compares very well with that reported earlier for the corresponding PF(6) (−) salt [Pandey et al. (1999 ▶). J. Organomet. Chem. 592, 278–282]. The [FeCl(4)](−) counter ion has...

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Autores principales: Štěpnička, Petr, Schulz, Jiří, Císařová, Ivana
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201229/
https://www.ncbi.nlm.nih.gov/pubmed/22058693
http://dx.doi.org/10.1107/S160053681103621X
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author Štěpnička, Petr
Schulz, Jiří
Císařová, Ivana
author_facet Štěpnička, Petr
Schulz, Jiří
Císařová, Ivana
author_sort Štěpnička, Petr
collection PubMed
description The mol­ecular geometry of the complex cation in the title structure, [(μ-Cl)(3){Ru(II)(η(6)-C(6)Me(6))}(2)][Fe(III)Cl(4)], compares very well with that reported earlier for the corresponding PF(6) (−) salt [Pandey et al. (1999 ▶). J. Organomet. Chem. 592, 278–282]. The [FeCl(4)](−) counter ion has a rather regular tetra­hedral geometry with Fe—Cl distances and Cl—Fe—Cl angles in the range 2.1891 (7)–2.2018 (8) Å and 107.10 (3)–110.56 (3)°, respectively. There are no significant inter­molecular inter­actions in the crystal except for some weak C—H⋯Cl contacts, which in turn indicates that the crystal packing is determined predominantly by electrostatic inter­actions between the ionic constituents.
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spelling pubmed-32012292011-11-06 Tri-μ-chlorido-bis­[(η(6)-hexa­methyl­benzene)­ruthenium(II)] tetra­chlorido­ferrate(III) Štěpnička, Petr Schulz, Jiří Císařová, Ivana Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The mol­ecular geometry of the complex cation in the title structure, [(μ-Cl)(3){Ru(II)(η(6)-C(6)Me(6))}(2)][Fe(III)Cl(4)], compares very well with that reported earlier for the corresponding PF(6) (−) salt [Pandey et al. (1999 ▶). J. Organomet. Chem. 592, 278–282]. The [FeCl(4)](−) counter ion has a rather regular tetra­hedral geometry with Fe—Cl distances and Cl—Fe—Cl angles in the range 2.1891 (7)–2.2018 (8) Å and 107.10 (3)–110.56 (3)°, respectively. There are no significant inter­molecular inter­actions in the crystal except for some weak C—H⋯Cl contacts, which in turn indicates that the crystal packing is determined predominantly by electrostatic inter­actions between the ionic constituents. International Union of Crystallography 2011-09-14 /pmc/articles/PMC3201229/ /pubmed/22058693 http://dx.doi.org/10.1107/S160053681103621X Text en © Štěpnička et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Štěpnička, Petr
Schulz, Jiří
Císařová, Ivana
Tri-μ-chlorido-bis­[(η(6)-hexa­methyl­benzene)­ruthenium(II)] tetra­chlorido­ferrate(III)
title Tri-μ-chlorido-bis­[(η(6)-hexa­methyl­benzene)­ruthenium(II)] tetra­chlorido­ferrate(III)
title_full Tri-μ-chlorido-bis­[(η(6)-hexa­methyl­benzene)­ruthenium(II)] tetra­chlorido­ferrate(III)
title_fullStr Tri-μ-chlorido-bis­[(η(6)-hexa­methyl­benzene)­ruthenium(II)] tetra­chlorido­ferrate(III)
title_full_unstemmed Tri-μ-chlorido-bis­[(η(6)-hexa­methyl­benzene)­ruthenium(II)] tetra­chlorido­ferrate(III)
title_short Tri-μ-chlorido-bis­[(η(6)-hexa­methyl­benzene)­ruthenium(II)] tetra­chlorido­ferrate(III)
title_sort tri-μ-chlorido-bis­[(η(6)-hexa­methyl­benzene)­ruthenium(ii)] tetra­chlorido­ferrate(iii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201229/
https://www.ncbi.nlm.nih.gov/pubmed/22058693
http://dx.doi.org/10.1107/S160053681103621X
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AT schulzjiri trimchloridobisē6hexamethylbenzenerutheniumiitetrachloridoferrateiii
AT cisarovaivana trimchloridobisē6hexamethylbenzenerutheniumiitetrachloridoferrateiii

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