Cargando…
1,4-Bis(1,1-dimethylpropyl)-2,5-dimethoxybenzene
The title compound, C(18)H(30)O(2), was prepared by Friedel–Crafts alkylation of 1,4-dimethoxybenzene with 2-methyl-2-butanol. The complete molecule is generated by the application of a crystallographic centre of inversion. The two methoxy groups are oriented in the same plane of the aromatic r...
Autor principal: | |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201239/ https://www.ncbi.nlm.nih.gov/pubmed/22058795 http://dx.doi.org/10.1107/S160053681103772X |
Sumario: | The title compound, C(18)H(30)O(2), was prepared by Friedel–Crafts alkylation of 1,4-dimethoxybenzene with 2-methyl-2-butanol. The complete molecule is generated by the application of a crystallographic centre of inversion. The two methoxy groups are oriented in the same plane of the aromatic ring [C—C—O—C torsion angle = 9.14 (16)°]. While one methyl group of the tert-pentyl substituent is coplanar with the benzene ring [C—C—C—C = 0.45 (15)°] and lies towards the less-hindered H atom, the other methyl and ethyl groups are directed to either side of the benzene ring [C—C—C—C torsion angles = 118.78 (12) and 59.11 (14)°, respectively]. In the crystal, the hydrophobic molecules pack to form a brick-wall-like architecture. |
---|