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1,4-Bis(1,1-dimethylpropyl)-2,5-dimethoxybenzene
The title compound, C(18)H(30)O(2), was prepared by Friedel–Crafts alkylation of 1,4-dimethoxybenzene with 2-methyl-2-butanol. The complete molecule is generated by the application of a crystallographic centre of inversion. The two methoxy groups are oriented in the same plane of the aromatic r...
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Formato: | Online Artículo Texto |
Lenguaje: | English |
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International Union of Crystallography
2011
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201239/ https://www.ncbi.nlm.nih.gov/pubmed/22058795 http://dx.doi.org/10.1107/S160053681103772X |
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author | Amimoto, Kiichi |
author_facet | Amimoto, Kiichi |
author_sort | Amimoto, Kiichi |
collection | PubMed |
description | The title compound, C(18)H(30)O(2), was prepared by Friedel–Crafts alkylation of 1,4-dimethoxybenzene with 2-methyl-2-butanol. The complete molecule is generated by the application of a crystallographic centre of inversion. The two methoxy groups are oriented in the same plane of the aromatic ring [C—C—O—C torsion angle = 9.14 (16)°]. While one methyl group of the tert-pentyl substituent is coplanar with the benzene ring [C—C—C—C = 0.45 (15)°] and lies towards the less-hindered H atom, the other methyl and ethyl groups are directed to either side of the benzene ring [C—C—C—C torsion angles = 118.78 (12) and 59.11 (14)°, respectively]. In the crystal, the hydrophobic molecules pack to form a brick-wall-like architecture. |
format | Online Article Text |
id | pubmed-3201239 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32012392011-11-06 1,4-Bis(1,1-dimethylpropyl)-2,5-dimethoxybenzene Amimoto, Kiichi Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(18)H(30)O(2), was prepared by Friedel–Crafts alkylation of 1,4-dimethoxybenzene with 2-methyl-2-butanol. The complete molecule is generated by the application of a crystallographic centre of inversion. The two methoxy groups are oriented in the same plane of the aromatic ring [C—C—O—C torsion angle = 9.14 (16)°]. While one methyl group of the tert-pentyl substituent is coplanar with the benzene ring [C—C—C—C = 0.45 (15)°] and lies towards the less-hindered H atom, the other methyl and ethyl groups are directed to either side of the benzene ring [C—C—C—C torsion angles = 118.78 (12) and 59.11 (14)°, respectively]. In the crystal, the hydrophobic molecules pack to form a brick-wall-like architecture. International Union of Crystallography 2011-09-30 /pmc/articles/PMC3201239/ /pubmed/22058795 http://dx.doi.org/10.1107/S160053681103772X Text en © Kiichi Amimoto 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Amimoto, Kiichi 1,4-Bis(1,1-dimethylpropyl)-2,5-dimethoxybenzene |
title | 1,4-Bis(1,1-dimethylpropyl)-2,5-dimethoxybenzene |
title_full | 1,4-Bis(1,1-dimethylpropyl)-2,5-dimethoxybenzene |
title_fullStr | 1,4-Bis(1,1-dimethylpropyl)-2,5-dimethoxybenzene |
title_full_unstemmed | 1,4-Bis(1,1-dimethylpropyl)-2,5-dimethoxybenzene |
title_short | 1,4-Bis(1,1-dimethylpropyl)-2,5-dimethoxybenzene |
title_sort | 1,4-bis(1,1-dimethylpropyl)-2,5-dimethoxybenzene |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201239/ https://www.ncbi.nlm.nih.gov/pubmed/22058795 http://dx.doi.org/10.1107/S160053681103772X |
work_keys_str_mv | AT amimotokiichi 14bis11dimethylpropyl25dimethoxybenzene |