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1,4-Bis(1,1-dimethyl­prop­yl)-2,5-dimeth­oxy­benzene

The title compound, C(18)H(30)O(2), was prepared by Friedel–Crafts alkyl­ation of 1,4-dimeth­oxy­benzene with 2-methyl-2-butanol. The complete mol­ecule is generated by the application of a crystallographic centre of inversion. The two meth­oxy groups are oriented in the same plane of the aromatic r...

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Autor principal: Amimoto, Kiichi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201239/
https://www.ncbi.nlm.nih.gov/pubmed/22058795
http://dx.doi.org/10.1107/S160053681103772X
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author Amimoto, Kiichi
author_facet Amimoto, Kiichi
author_sort Amimoto, Kiichi
collection PubMed
description The title compound, C(18)H(30)O(2), was prepared by Friedel–Crafts alkyl­ation of 1,4-dimeth­oxy­benzene with 2-methyl-2-butanol. The complete mol­ecule is generated by the application of a crystallographic centre of inversion. The two meth­oxy groups are oriented in the same plane of the aromatic ring [C—C—O—C torsion angle = 9.14 (16)°]. While one methyl group of the tert-pentyl substituent is coplanar with the benzene ring [C—C—C—C = 0.45 (15)°] and lies towards the less-hindered H atom, the other methyl and ethyl groups are directed to either side of the benzene ring [C—C—C—C torsion angles = 118.78 (12) and 59.11 (14)°, respectively]. In the crystal, the hydro­phobic mol­ecules pack to form a brick-wall-like architecture.
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spelling pubmed-32012392011-11-06 1,4-Bis(1,1-dimethyl­prop­yl)-2,5-dimeth­oxy­benzene Amimoto, Kiichi Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(18)H(30)O(2), was prepared by Friedel–Crafts alkyl­ation of 1,4-dimeth­oxy­benzene with 2-methyl-2-butanol. The complete mol­ecule is generated by the application of a crystallographic centre of inversion. The two meth­oxy groups are oriented in the same plane of the aromatic ring [C—C—O—C torsion angle = 9.14 (16)°]. While one methyl group of the tert-pentyl substituent is coplanar with the benzene ring [C—C—C—C = 0.45 (15)°] and lies towards the less-hindered H atom, the other methyl and ethyl groups are directed to either side of the benzene ring [C—C—C—C torsion angles = 118.78 (12) and 59.11 (14)°, respectively]. In the crystal, the hydro­phobic mol­ecules pack to form a brick-wall-like architecture. International Union of Crystallography 2011-09-30 /pmc/articles/PMC3201239/ /pubmed/22058795 http://dx.doi.org/10.1107/S160053681103772X Text en © Kiichi Amimoto 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Amimoto, Kiichi
1,4-Bis(1,1-dimethyl­prop­yl)-2,5-dimeth­oxy­benzene
title 1,4-Bis(1,1-dimethyl­prop­yl)-2,5-dimeth­oxy­benzene
title_full 1,4-Bis(1,1-dimethyl­prop­yl)-2,5-dimeth­oxy­benzene
title_fullStr 1,4-Bis(1,1-dimethyl­prop­yl)-2,5-dimeth­oxy­benzene
title_full_unstemmed 1,4-Bis(1,1-dimethyl­prop­yl)-2,5-dimeth­oxy­benzene
title_short 1,4-Bis(1,1-dimethyl­prop­yl)-2,5-dimeth­oxy­benzene
title_sort 1,4-bis(1,1-dimethyl­prop­yl)-2,5-dimeth­oxy­benzene
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201239/
https://www.ncbi.nlm.nih.gov/pubmed/22058795
http://dx.doi.org/10.1107/S160053681103772X
work_keys_str_mv AT amimotokiichi 14bis11dimethylpropyl25dimethoxybenzene