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catena-Poly[[[tetraaquanickel(II)]-μ-4,4′-bipyridyl-κ(2) N:N′] 3,3′-(p-phenylene)diacrylate]
In the title compound, {[Ni(C(10)H(8)N(2))(H(2)O)(4)](C(12)H(8)O(4))}(n), the Ni(II), 4,4′-bipyridyl (bipy) and 3,3′-(p-phenylene)diacrylate (L (2−)) moieties are situated on inversion centres. The bipy ligands bridge Ni(II) ions into positively charged polymeric chains along [101]. The Ni(II) atom...
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201244/ https://www.ncbi.nlm.nih.gov/pubmed/22064763 http://dx.doi.org/10.1107/S1600536811036993 |
Sumario: | In the title compound, {[Ni(C(10)H(8)N(2))(H(2)O)(4)](C(12)H(8)O(4))}(n), the Ni(II), 4,4′-bipyridyl (bipy) and 3,3′-(p-phenylene)diacrylate (L (2−)) moieties are situated on inversion centres. The bipy ligands bridge Ni(II) ions into positively charged polymeric chains along [101]. The Ni(II) atom is coordinated by two N atoms from two bipy ligands and four water molecules in a distorted octahedral geometry. L (2−) anions interact with the polymeric chains via O–H⋯O hydrogen bonds, forming a three-dimensional supramolecular network. |
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