catena-Poly[[[tetra­aqua­nickel(II)]-μ-4,4′-bipyridyl-κ(2) N:N′] 3,3′-(p-phenyl­ene)diacrylate]

In the title compound, {[Ni(C(10)H(8)N(2))(H(2)O)(4)](C(12)H(8)O(4))}(n), the Ni(II), 4,4′-bipyridyl (bipy) and 3,3′-(p-phenyl­ene)diacrylate (L (2−)) moieties are situated on inversion centres. The bipy ligands bridge Ni(II) ions into positively charged polymeric chains along [101]. The Ni(II) atom...

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Detalles Bibliográficos
Autor principal: Li, Ni-Ya
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201244/
https://www.ncbi.nlm.nih.gov/pubmed/22064763
http://dx.doi.org/10.1107/S1600536811036993
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author Li, Ni-Ya
author_facet Li, Ni-Ya
author_sort Li, Ni-Ya
collection PubMed
description In the title compound, {[Ni(C(10)H(8)N(2))(H(2)O)(4)](C(12)H(8)O(4))}(n), the Ni(II), 4,4′-bipyridyl (bipy) and 3,3′-(p-phenyl­ene)diacrylate (L (2−)) moieties are situated on inversion centres. The bipy ligands bridge Ni(II) ions into positively charged polymeric chains along [101]. The Ni(II) atom is coordinated by two N atoms from two bipy ligands and four water mol­ecules in a distorted octa­hedral geometry. L (2−) anions inter­act with the polymeric chains via O–H⋯O hydrogen bonds, forming a three-dimensional supra­molecular network.
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spelling pubmed-32012442011-11-06 catena-Poly[[[tetra­aqua­nickel(II)]-μ-4,4′-bipyridyl-κ(2) N:N′] 3,3′-(p-phenyl­ene)diacrylate] Li, Ni-Ya Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, {[Ni(C(10)H(8)N(2))(H(2)O)(4)](C(12)H(8)O(4))}(n), the Ni(II), 4,4′-bipyridyl (bipy) and 3,3′-(p-phenyl­ene)diacrylate (L (2−)) moieties are situated on inversion centres. The bipy ligands bridge Ni(II) ions into positively charged polymeric chains along [101]. The Ni(II) atom is coordinated by two N atoms from two bipy ligands and four water mol­ecules in a distorted octa­hedral geometry. L (2−) anions inter­act with the polymeric chains via O–H⋯O hydrogen bonds, forming a three-dimensional supra­molecular network. International Union of Crystallography 2011-09-17 /pmc/articles/PMC3201244/ /pubmed/22064763 http://dx.doi.org/10.1107/S1600536811036993 Text en © Ni-Ya Li 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Li, Ni-Ya
catena-Poly[[[tetra­aqua­nickel(II)]-μ-4,4′-bipyridyl-κ(2) N:N′] 3,3′-(p-phenyl­ene)diacrylate]
title catena-Poly[[[tetra­aqua­nickel(II)]-μ-4,4′-bipyridyl-κ(2) N:N′] 3,3′-(p-phenyl­ene)diacrylate]
title_full catena-Poly[[[tetra­aqua­nickel(II)]-μ-4,4′-bipyridyl-κ(2) N:N′] 3,3′-(p-phenyl­ene)diacrylate]
title_fullStr catena-Poly[[[tetra­aqua­nickel(II)]-μ-4,4′-bipyridyl-κ(2) N:N′] 3,3′-(p-phenyl­ene)diacrylate]
title_full_unstemmed catena-Poly[[[tetra­aqua­nickel(II)]-μ-4,4′-bipyridyl-κ(2) N:N′] 3,3′-(p-phenyl­ene)diacrylate]
title_short catena-Poly[[[tetra­aqua­nickel(II)]-μ-4,4′-bipyridyl-κ(2) N:N′] 3,3′-(p-phenyl­ene)diacrylate]
title_sort catena-poly[[[tetra­aqua­nickel(ii)]-μ-4,4′-bipyridyl-κ(2) n:n′] 3,3′-(p-phenyl­ene)diacrylate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201244/
https://www.ncbi.nlm.nih.gov/pubmed/22064763
http://dx.doi.org/10.1107/S1600536811036993
work_keys_str_mv AT liniya catenapolytetraaquanickeliim44bipyridylk2nn33pphenylenediacrylate

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