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Dichlorido(2,3-di-2-pyridyl­pyrazine-κ(2) N (1),N (2))platinum(II)

The Pt(II) ion in the title complex, [PtCl(2)(C(14)H(10)N(4))], is four-coordinated in a distorted square-planar environment by two N atoms of a chelating 2,3-di-2-pyridyl­pyrazine ligand and two chloride anions. The pyridyl ring coordinated to the Pt(II) atom is inclined slightly to its carrier pyr...

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Autor principal: Ha, Kwang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201246/
https://www.ncbi.nlm.nih.gov/pubmed/22064814
http://dx.doi.org/10.1107/S1600536811038906
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author Ha, Kwang
author_facet Ha, Kwang
author_sort Ha, Kwang
collection PubMed
description The Pt(II) ion in the title complex, [PtCl(2)(C(14)H(10)N(4))], is four-coordinated in a distorted square-planar environment by two N atoms of a chelating 2,3-di-2-pyridyl­pyrazine ligand and two chloride anions. The pyridyl ring coordinated to the Pt(II) atom is inclined slightly to its carrier pyrazine ring [dihedral angle = 13.5 (1)°], whereas the uncoordinated pyridyl ring is inclined considerably to the pyrazine ring [dihedral angle = 54.3 (2)°]. The dihedral angle between the two pyridyl rings is 59.2 (2)°. In the crystal, the complexes are assembled through inter­molecular C—H⋯N and C—H⋯Cl hydrogen bonds, forming a three-dimensional network. Intra­molecular C—H⋯N and C—H⋯Cl hydrogen bonds are also present.
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spelling pubmed-32012462011-11-06 Dichlorido(2,3-di-2-pyridyl­pyrazine-κ(2) N (1),N (2))platinum(II) Ha, Kwang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Pt(II) ion in the title complex, [PtCl(2)(C(14)H(10)N(4))], is four-coordinated in a distorted square-planar environment by two N atoms of a chelating 2,3-di-2-pyridyl­pyrazine ligand and two chloride anions. The pyridyl ring coordinated to the Pt(II) atom is inclined slightly to its carrier pyrazine ring [dihedral angle = 13.5 (1)°], whereas the uncoordinated pyridyl ring is inclined considerably to the pyrazine ring [dihedral angle = 54.3 (2)°]. The dihedral angle between the two pyridyl rings is 59.2 (2)°. In the crystal, the complexes are assembled through inter­molecular C—H⋯N and C—H⋯Cl hydrogen bonds, forming a three-dimensional network. Intra­molecular C—H⋯N and C—H⋯Cl hydrogen bonds are also present. International Union of Crystallography 2011-09-30 /pmc/articles/PMC3201246/ /pubmed/22064814 http://dx.doi.org/10.1107/S1600536811038906 Text en © Kwang Ha 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Ha, Kwang
Dichlorido(2,3-di-2-pyridyl­pyrazine-κ(2) N (1),N (2))platinum(II)
title Dichlorido(2,3-di-2-pyridyl­pyrazine-κ(2) N (1),N (2))platinum(II)
title_full Dichlorido(2,3-di-2-pyridyl­pyrazine-κ(2) N (1),N (2))platinum(II)
title_fullStr Dichlorido(2,3-di-2-pyridyl­pyrazine-κ(2) N (1),N (2))platinum(II)
title_full_unstemmed Dichlorido(2,3-di-2-pyridyl­pyrazine-κ(2) N (1),N (2))platinum(II)
title_short Dichlorido(2,3-di-2-pyridyl­pyrazine-κ(2) N (1),N (2))platinum(II)
title_sort dichlorido(2,3-di-2-pyridyl­pyrazine-κ(2) n (1),n (2))platinum(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201246/
https://www.ncbi.nlm.nih.gov/pubmed/22064814
http://dx.doi.org/10.1107/S1600536811038906
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