Dichlorido(η(4)-cyclo­octa-1,5-diene)bis­(propane­nitrile-κN)ruthenium(II)

In the title complex, [RuCl(2)(C(8)H(12))(C(3)H(5)N)(2)], the metal ion is coordinated to both double bonds of the cyclo­octa-1,5-diene ligand, two chloride ions (in cis positions) and two N-atom donors from two propane­nitrile mol­ecules that complete the coordination sphere for the neutral complex...

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Detalles Bibliográficos
Autores principales: Chiririwa, Haleden, Meijboom, Reinout
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201259/
https://www.ncbi.nlm.nih.gov/pubmed/22065023
http://dx.doi.org/10.1107/S1600536811035379
Descripción
Sumario:In the title complex, [RuCl(2)(C(8)H(12))(C(3)H(5)N)(2)], the metal ion is coordinated to both double bonds of the cyclo­octa-1,5-diene ligand, two chloride ions (in cis positions) and two N-atom donors from two propane­nitrile mol­ecules that complete the coordination sphere for the neutral complex. The coordination around the Ru(II) atom can thus be considered as octa­hedral with slight trigonal distortion.

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