Dichlorido(η(4)-cyclo­octa-1,5-diene)bis­(propane­nitrile-κN)ruthenium(II)

In the title complex, [RuCl(2)(C(8)H(12))(C(3)H(5)N)(2)], the metal ion is coordinated to both double bonds of the cyclo­octa-1,5-diene ligand, two chloride ions (in cis positions) and two N-atom donors from two propane­nitrile mol­ecules that complete the coordination sphere for the neutral complex...

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Detalles Bibliográficos
Autores principales: Chiririwa, Haleden, Meijboom, Reinout
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201259/
https://www.ncbi.nlm.nih.gov/pubmed/22065023
http://dx.doi.org/10.1107/S1600536811035379
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author Chiririwa, Haleden
Meijboom, Reinout
author_facet Chiririwa, Haleden
Meijboom, Reinout
author_sort Chiririwa, Haleden
collection PubMed
description In the title complex, [RuCl(2)(C(8)H(12))(C(3)H(5)N)(2)], the metal ion is coordinated to both double bonds of the cyclo­octa-1,5-diene ligand, two chloride ions (in cis positions) and two N-atom donors from two propane­nitrile mol­ecules that complete the coordination sphere for the neutral complex. The coordination around the Ru(II) atom can thus be considered as octa­hedral with slight trigonal distortion.
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spelling pubmed-32012592011-11-06 Dichlorido(η(4)-cyclo­octa-1,5-diene)bis­(propane­nitrile-κN)ruthenium(II) Chiririwa, Haleden Meijboom, Reinout Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [RuCl(2)(C(8)H(12))(C(3)H(5)N)(2)], the metal ion is coordinated to both double bonds of the cyclo­octa-1,5-diene ligand, two chloride ions (in cis positions) and two N-atom donors from two propane­nitrile mol­ecules that complete the coordination sphere for the neutral complex. The coordination around the Ru(II) atom can thus be considered as octa­hedral with slight trigonal distortion. International Union of Crystallography 2011-09-14 /pmc/articles/PMC3201259/ /pubmed/22065023 http://dx.doi.org/10.1107/S1600536811035379 Text en © Chiririwa and Meijboom 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Chiririwa, Haleden
Meijboom, Reinout
Dichlorido(η(4)-cyclo­octa-1,5-diene)bis­(propane­nitrile-κN)ruthenium(II)
title Dichlorido(η(4)-cyclo­octa-1,5-diene)bis­(propane­nitrile-κN)ruthenium(II)
title_full Dichlorido(η(4)-cyclo­octa-1,5-diene)bis­(propane­nitrile-κN)ruthenium(II)
title_fullStr Dichlorido(η(4)-cyclo­octa-1,5-diene)bis­(propane­nitrile-κN)ruthenium(II)
title_full_unstemmed Dichlorido(η(4)-cyclo­octa-1,5-diene)bis­(propane­nitrile-κN)ruthenium(II)
title_short Dichlorido(η(4)-cyclo­octa-1,5-diene)bis­(propane­nitrile-κN)ruthenium(II)
title_sort dichlorido(η(4)-cyclo­octa-1,5-diene)bis­(propane­nitrile-κn)ruthenium(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201259/
https://www.ncbi.nlm.nih.gov/pubmed/22065023
http://dx.doi.org/10.1107/S1600536811035379
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