Tris(2,2′-bi-1H-imidazole-κ(2) N (3),N (3′))cobalt(II) hydrogen phosphate

The title compound, [Co(C(6)H(6)N(4))(3)]HPO(4), was synthesized under hydro­thermal conditions. In the cation, the Co(II) atom is octa­hedrally coordinated by six N atoms from three 2,2′-bi-1H-imidazole ligands [Co—N bond lengths are in the range 2.084 (5)–2.133 (6) Å]. Inter­molecular N—H⋯O hydrog...

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Detalles Bibliográficos
Autores principales: Liang, Zhiqiang, Wang, Fuxiang, Wu, Qihui, Zhi, Xia, Pan, Qinhe
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201263/
https://www.ncbi.nlm.nih.gov/pubmed/22058703
http://dx.doi.org/10.1107/S1600536811037299
Descripción
Sumario:The title compound, [Co(C(6)H(6)N(4))(3)]HPO(4), was synthesized under hydro­thermal conditions. In the cation, the Co(II) atom is octa­hedrally coordinated by six N atoms from three 2,2′-bi-1H-imidazole ligands [Co—N bond lengths are in the range 2.084 (5)–2.133 (6) Å]. Inter­molecular N—H⋯O hydrogen bonds form an extensive hydrogen-bonding network, which links cations and anions into a three-dimensional crystal structure.

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