Tris(2,2′-bi-1H-imidazole-κ(2) N (3),N (3′))cobalt(II) hydrogen phosphate

The title compound, [Co(C(6)H(6)N(4))(3)]HPO(4), was synthesized under hydro­thermal conditions. In the cation, the Co(II) atom is octa­hedrally coordinated by six N atoms from three 2,2′-bi-1H-imidazole ligands [Co—N bond lengths are in the range 2.084 (5)–2.133 (6) Å]. Inter­molecular N—H⋯O hydrog...

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Detalles Bibliográficos
Autores principales: Liang, Zhiqiang, Wang, Fuxiang, Wu, Qihui, Zhi, Xia, Pan, Qinhe
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201263/
https://www.ncbi.nlm.nih.gov/pubmed/22058703
http://dx.doi.org/10.1107/S1600536811037299
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author Liang, Zhiqiang
Wang, Fuxiang
Wu, Qihui
Zhi, Xia
Pan, Qinhe
author_facet Liang, Zhiqiang
Wang, Fuxiang
Wu, Qihui
Zhi, Xia
Pan, Qinhe
author_sort Liang, Zhiqiang
collection PubMed
description The title compound, [Co(C(6)H(6)N(4))(3)]HPO(4), was synthesized under hydro­thermal conditions. In the cation, the Co(II) atom is octa­hedrally coordinated by six N atoms from three 2,2′-bi-1H-imidazole ligands [Co—N bond lengths are in the range 2.084 (5)–2.133 (6) Å]. Inter­molecular N—H⋯O hydrogen bonds form an extensive hydrogen-bonding network, which links cations and anions into a three-dimensional crystal structure.
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spelling pubmed-32012632011-11-06 Tris(2,2′-bi-1H-imidazole-κ(2) N (3),N (3′))cobalt(II) hydrogen phosphate Liang, Zhiqiang Wang, Fuxiang Wu, Qihui Zhi, Xia Pan, Qinhe Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Co(C(6)H(6)N(4))(3)]HPO(4), was synthesized under hydro­thermal conditions. In the cation, the Co(II) atom is octa­hedrally coordinated by six N atoms from three 2,2′-bi-1H-imidazole ligands [Co—N bond lengths are in the range 2.084 (5)–2.133 (6) Å]. Inter­molecular N—H⋯O hydrogen bonds form an extensive hydrogen-bonding network, which links cations and anions into a three-dimensional crystal structure. International Union of Crystallography 2011-09-17 /pmc/articles/PMC3201263/ /pubmed/22058703 http://dx.doi.org/10.1107/S1600536811037299 Text en © Liang et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Liang, Zhiqiang
Wang, Fuxiang
Wu, Qihui
Zhi, Xia
Pan, Qinhe
Tris(2,2′-bi-1H-imidazole-κ(2) N (3),N (3′))cobalt(II) hydrogen phosphate
title Tris(2,2′-bi-1H-imidazole-κ(2) N (3),N (3′))cobalt(II) hydrogen phosphate
title_full Tris(2,2′-bi-1H-imidazole-κ(2) N (3),N (3′))cobalt(II) hydrogen phosphate
title_fullStr Tris(2,2′-bi-1H-imidazole-κ(2) N (3),N (3′))cobalt(II) hydrogen phosphate
title_full_unstemmed Tris(2,2′-bi-1H-imidazole-κ(2) N (3),N (3′))cobalt(II) hydrogen phosphate
title_short Tris(2,2′-bi-1H-imidazole-κ(2) N (3),N (3′))cobalt(II) hydrogen phosphate
title_sort tris(2,2′-bi-1h-imidazole-κ(2) n (3),n (3′))cobalt(ii) hydrogen phosphate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201263/
https://www.ncbi.nlm.nih.gov/pubmed/22058703
http://dx.doi.org/10.1107/S1600536811037299
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