Cargando…
(Z)-Methyl 2-[(4-bromo-2-formylphenoxy)methyl]-3-o-tolylacrylate
In the title compound, C(19)H(17)BrO(4), the dihedral angle between the two benzene rings is 82.1 (1)°. The molecular structure is stabilized by an intramolecular C—H⋯O hydrogen bond which generates an S(7) ring motif. The crystal packing is stabilized by intermolecular C—H⋯O hydrogen bonds and C...
| Autores principales: | , , , , |
|---|---|
| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2011
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201264/ https://www.ncbi.nlm.nih.gov/pubmed/22065120 http://dx.doi.org/10.1107/S1600536811037731 |
| _version_ | 1782214834810519552 |
|---|---|
| author | Vijayakumar, S. Madhanraj, R. Murugavel, S. Selvakumar, R. Bakthadoss, M. |
| author_facet | Vijayakumar, S. Madhanraj, R. Murugavel, S. Selvakumar, R. Bakthadoss, M. |
| author_sort | Vijayakumar, S. |
| collection | PubMed |
| description | In the title compound, C(19)H(17)BrO(4), the dihedral angle between the two benzene rings is 82.1 (1)°. The molecular structure is stabilized by an intramolecular C—H⋯O hydrogen bond which generates an S(7) ring motif. The crystal packing is stabilized by intermolecular C—H⋯O hydrogen bonds and C—H⋯π interactions. Intermolecular C—H⋯O interactions are involved in the formation of centrosymmetric R (2) (2)(16) dimers, which are connected into supramolecular tapes running along the [100] direction. |
| format | Online Article Text |
| id | pubmed-3201264 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-32012642011-11-06 (Z)-Methyl 2-[(4-bromo-2-formylphenoxy)methyl]-3-o-tolylacrylate Vijayakumar, S. Madhanraj, R. Murugavel, S. Selvakumar, R. Bakthadoss, M. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(19)H(17)BrO(4), the dihedral angle between the two benzene rings is 82.1 (1)°. The molecular structure is stabilized by an intramolecular C—H⋯O hydrogen bond which generates an S(7) ring motif. The crystal packing is stabilized by intermolecular C—H⋯O hydrogen bonds and C—H⋯π interactions. Intermolecular C—H⋯O interactions are involved in the formation of centrosymmetric R (2) (2)(16) dimers, which are connected into supramolecular tapes running along the [100] direction. International Union of Crystallography 2011-09-20 /pmc/articles/PMC3201264/ /pubmed/22065120 http://dx.doi.org/10.1107/S1600536811037731 Text en © Vijayakumar et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Organic Papers Vijayakumar, S. Madhanraj, R. Murugavel, S. Selvakumar, R. Bakthadoss, M. (Z)-Methyl 2-[(4-bromo-2-formylphenoxy)methyl]-3-o-tolylacrylate |
| title | (Z)-Methyl 2-[(4-bromo-2-formylphenoxy)methyl]-3-o-tolylacrylate |
| title_full | (Z)-Methyl 2-[(4-bromo-2-formylphenoxy)methyl]-3-o-tolylacrylate |
| title_fullStr | (Z)-Methyl 2-[(4-bromo-2-formylphenoxy)methyl]-3-o-tolylacrylate |
| title_full_unstemmed | (Z)-Methyl 2-[(4-bromo-2-formylphenoxy)methyl]-3-o-tolylacrylate |
| title_short | (Z)-Methyl 2-[(4-bromo-2-formylphenoxy)methyl]-3-o-tolylacrylate |
| title_sort | (z)-methyl 2-[(4-bromo-2-formylphenoxy)methyl]-3-o-tolylacrylate |
| topic | Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201264/ https://www.ncbi.nlm.nih.gov/pubmed/22065120 http://dx.doi.org/10.1107/S1600536811037731 |
| work_keys_str_mv | AT vijayakumars zmethyl24bromo2formylphenoxymethyl3otolylacrylate AT madhanrajr zmethyl24bromo2formylphenoxymethyl3otolylacrylate AT murugavels zmethyl24bromo2formylphenoxymethyl3otolylacrylate AT selvakumarr zmethyl24bromo2formylphenoxymethyl3otolylacrylate AT bakthadossm zmethyl24bromo2formylphenoxymethyl3otolylacrylate |