Ethyl 2-[2-(3-meth­oxy­phen­yl)hydrazinyl­idene]-3-oxobutano­ate

The title compound, C(13)H(16)N(2)O(4), is approximately planar (r.m.s. deviation = 0.065 Å for the 19 non-H atoms). An intra­molecular N—H⋯O hydrogen bond generates an S(6) ring motif and the mol­ecule adopts an E conformation with respect to the central C=N double bond. In the crystal, pairs of in...

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Autores principales: Fun, Hoong-Kun, Asik, Safra Izuani Jama, Razak, Ibrahim Abdul, Shetty, Shobhitha, Kalluraya, Balakrishna
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201266/
https://www.ncbi.nlm.nih.gov/pubmed/22065239
http://dx.doi.org/10.1107/S1600536811039444
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author Fun, Hoong-Kun
Asik, Safra Izuani Jama
Razak, Ibrahim Abdul
Shetty, Shobhitha
Kalluraya, Balakrishna
author_facet Fun, Hoong-Kun
Asik, Safra Izuani Jama
Razak, Ibrahim Abdul
Shetty, Shobhitha
Kalluraya, Balakrishna
author_sort Fun, Hoong-Kun
collection PubMed
description The title compound, C(13)H(16)N(2)O(4), is approximately planar (r.m.s. deviation = 0.065 Å for the 19 non-H atoms). An intra­molecular N—H⋯O hydrogen bond generates an S(6) ring motif and the mol­ecule adopts an E conformation with respect to the central C=N double bond. In the crystal, pairs of inter­molecular C—H⋯O hydrogen bonds link adjacent mol­ecules into inversion dimers. The crystal structure also features weak C—H⋯π inter­actions.
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spelling pubmed-32012662011-11-06 Ethyl 2-[2-(3-meth­oxy­phen­yl)hydrazinyl­idene]-3-oxobutano­ate Fun, Hoong-Kun Asik, Safra Izuani Jama Razak, Ibrahim Abdul Shetty, Shobhitha Kalluraya, Balakrishna Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(13)H(16)N(2)O(4), is approximately planar (r.m.s. deviation = 0.065 Å for the 19 non-H atoms). An intra­molecular N—H⋯O hydrogen bond generates an S(6) ring motif and the mol­ecule adopts an E conformation with respect to the central C=N double bond. In the crystal, pairs of inter­molecular C—H⋯O hydrogen bonds link adjacent mol­ecules into inversion dimers. The crystal structure also features weak C—H⋯π inter­actions. International Union of Crystallography 2011-09-30 /pmc/articles/PMC3201266/ /pubmed/22065239 http://dx.doi.org/10.1107/S1600536811039444 Text en © Fun et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Fun, Hoong-Kun
Asik, Safra Izuani Jama
Razak, Ibrahim Abdul
Shetty, Shobhitha
Kalluraya, Balakrishna
Ethyl 2-[2-(3-meth­oxy­phen­yl)hydrazinyl­idene]-3-oxobutano­ate
title Ethyl 2-[2-(3-meth­oxy­phen­yl)hydrazinyl­idene]-3-oxobutano­ate
title_full Ethyl 2-[2-(3-meth­oxy­phen­yl)hydrazinyl­idene]-3-oxobutano­ate
title_fullStr Ethyl 2-[2-(3-meth­oxy­phen­yl)hydrazinyl­idene]-3-oxobutano­ate
title_full_unstemmed Ethyl 2-[2-(3-meth­oxy­phen­yl)hydrazinyl­idene]-3-oxobutano­ate
title_short Ethyl 2-[2-(3-meth­oxy­phen­yl)hydrazinyl­idene]-3-oxobutano­ate
title_sort ethyl 2-[2-(3-meth­oxy­phen­yl)hydrazinyl­idene]-3-oxobutano­ate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201266/
https://www.ncbi.nlm.nih.gov/pubmed/22065239
http://dx.doi.org/10.1107/S1600536811039444
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