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2,2′-[1,5-Bis(4-aminophenyl)-1,5-dihydrobenzo[1,2-d;4,5-d′]diimidazole-2,6-diyl]diphenol
The title molecule, C(32)H(24)N(6)O(2), has a crystallographic inversion centre in the middle of the benzodiimidazole core. It exists as the enol–imine tautomeric form and exhibits a strong intramolecular O—H⋯N hydrogen bond. The dihedral angles between the planes of the 2-hydroxyphenyl and 4-am...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201269/ https://www.ncbi.nlm.nih.gov/pubmed/22065416 http://dx.doi.org/10.1107/S1600536811036737 |
Sumario: | The title molecule, C(32)H(24)N(6)O(2), has a crystallographic inversion centre in the middle of the benzodiimidazole core. It exists as the enol–imine tautomeric form and exhibits a strong intramolecular O—H⋯N hydrogen bond. The dihedral angles between the planes of the 2-hydroxyphenyl and 4-aminophenyl substituents and the plane of the benzodiimidazole unit [12.69 (8) and 84.71 (8)°, respectively] differ significantly due to steric reasons. In the crystal, molecules are linked by C—H⋯π interactions, forming a two-dimensional network. |
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