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2,2′-[1,5-Bis(4-amino­phen­yl)-1,5-dihydro­benzo[1,2-d;4,5-d′]diimidazole-2,6-di­yl]diphenol

The title mol­ecule, C(32)H(24)N(6)O(2), has a crystallographic inversion centre in the middle of the benzodiimidazole core. It exists as the enol–imine tautomeric form and exhibits a strong intra­molecular O—H⋯N hydrogen bond. The dihedral angles between the planes of the 2-hy­droxy­phenyl and 4-am...

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Detalles Bibliográficos
Autores principales: Blagus, Anita, Kaitner, Branko
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201269/
https://www.ncbi.nlm.nih.gov/pubmed/22065416
http://dx.doi.org/10.1107/S1600536811036737
Descripción
Sumario:The title mol­ecule, C(32)H(24)N(6)O(2), has a crystallographic inversion centre in the middle of the benzodiimidazole core. It exists as the enol–imine tautomeric form and exhibits a strong intra­molecular O—H⋯N hydrogen bond. The dihedral angles between the planes of the 2-hy­droxy­phenyl and 4-amino­phenyl substituents and the plane of the benzodiimidazole unit [12.69 (8) and 84.71 (8)°, respectively] differ significantly due to steric reasons. In the crystal, mol­ecules are linked by C—H⋯π inter­actions, forming a two-dimensional network.