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3-Amino-1-methyl-9,10-dihydrophenanthrene-2,4-dicarbonitrile
The asymmetric unit of the title compound, C(17)H(13)N(3), contains two independent molecules, which are non-planar as they are buckled owing to the ethylene portion. The dihedral angle between the benzene rings is 26.4 (1)° in one molecule and 32.9 (1)° in the other. In the crystal, the molecul...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201274/ https://www.ncbi.nlm.nih.gov/pubmed/22065653 http://dx.doi.org/10.1107/S1600536811035008 |
Sumario: | The asymmetric unit of the title compound, C(17)H(13)N(3), contains two independent molecules, which are non-planar as they are buckled owing to the ethylene portion. The dihedral angle between the benzene rings is 26.4 (1)° in one molecule and 32.9 (1)° in the other. In the crystal, the molecules are disposed about a false inversion center, and are linked by two N—H⋯N hydrogen bonds, generating a dimer. The dimers are linked by further N—H⋯N hydrogen bonds, resulting in a chain that runs along the longest axis of the orthorhombic unit cell. |
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