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3-Amino-1-methyl-9,10-dihydrophenanthrene-2,4-dicarbonitrile
The asymmetric unit of the title compound, C(17)H(13)N(3), contains two independent molecules, which are non-planar as they are buckled owing to the ethylene portion. The dihedral angle between the benzene rings is 26.4 (1)° in one molecule and 32.9 (1)° in the other. In the crystal, the molecul...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2011
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201274/ https://www.ncbi.nlm.nih.gov/pubmed/22065653 http://dx.doi.org/10.1107/S1600536811035008 |
| _version_ | 1782214837031403520 |
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| author | Al-Youbi, Abdulrahman O. Asiri, Abdullah M. Faidallah, Hassan M. Alamry, Khalid A. Ng, Seik Weng |
| author_facet | Al-Youbi, Abdulrahman O. Asiri, Abdullah M. Faidallah, Hassan M. Alamry, Khalid A. Ng, Seik Weng |
| author_sort | Al-Youbi, Abdulrahman O. |
| collection | PubMed |
| description | The asymmetric unit of the title compound, C(17)H(13)N(3), contains two independent molecules, which are non-planar as they are buckled owing to the ethylene portion. The dihedral angle between the benzene rings is 26.4 (1)° in one molecule and 32.9 (1)° in the other. In the crystal, the molecules are disposed about a false inversion center, and are linked by two N—H⋯N hydrogen bonds, generating a dimer. The dimers are linked by further N—H⋯N hydrogen bonds, resulting in a chain that runs along the longest axis of the orthorhombic unit cell. |
| format | Online Article Text |
| id | pubmed-3201274 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-32012742011-11-06 3-Amino-1-methyl-9,10-dihydrophenanthrene-2,4-dicarbonitrile Al-Youbi, Abdulrahman O. Asiri, Abdullah M. Faidallah, Hassan M. Alamry, Khalid A. Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(17)H(13)N(3), contains two independent molecules, which are non-planar as they are buckled owing to the ethylene portion. The dihedral angle between the benzene rings is 26.4 (1)° in one molecule and 32.9 (1)° in the other. In the crystal, the molecules are disposed about a false inversion center, and are linked by two N—H⋯N hydrogen bonds, generating a dimer. The dimers are linked by further N—H⋯N hydrogen bonds, resulting in a chain that runs along the longest axis of the orthorhombic unit cell. International Union of Crystallography 2011-09-14 /pmc/articles/PMC3201274/ /pubmed/22065653 http://dx.doi.org/10.1107/S1600536811035008 Text en © Al-Youbi et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Organic Papers Al-Youbi, Abdulrahman O. Asiri, Abdullah M. Faidallah, Hassan M. Alamry, Khalid A. Ng, Seik Weng 3-Amino-1-methyl-9,10-dihydrophenanthrene-2,4-dicarbonitrile |
| title | 3-Amino-1-methyl-9,10-dihydrophenanthrene-2,4-dicarbonitrile |
| title_full | 3-Amino-1-methyl-9,10-dihydrophenanthrene-2,4-dicarbonitrile |
| title_fullStr | 3-Amino-1-methyl-9,10-dihydrophenanthrene-2,4-dicarbonitrile |
| title_full_unstemmed | 3-Amino-1-methyl-9,10-dihydrophenanthrene-2,4-dicarbonitrile |
| title_short | 3-Amino-1-methyl-9,10-dihydrophenanthrene-2,4-dicarbonitrile |
| title_sort | 3-amino-1-methyl-9,10-dihydrophenanthrene-2,4-dicarbonitrile |
| topic | Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201274/ https://www.ncbi.nlm.nih.gov/pubmed/22065653 http://dx.doi.org/10.1107/S1600536811035008 |
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