2,6,6-Trimethyl­cyclo­hexene-1-carbaldehyde oxime

In the crystal of the title compound C(10)H(17)NO, synthesized by the reaction of β-cyclo­citral with hydroxyl­amine hydro­chloride, inversion-related mol­ecules are linked by a pair of O—H⋯N hydrogen-bonding inter­actions between the oxime functionalities, forming R (2) (2)(6) loops. The molecular...

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Detalles Bibliográficos
Autores principales: Parthasarathy, Rajasekaran, Jenniefer, Samson Jegan, Muthiah, Packianathan Thomas, Sulochana, Nagarajan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201277/
https://www.ncbi.nlm.nih.gov/pubmed/22065695
http://dx.doi.org/10.1107/S1600536811037895
Descripción
Sumario:In the crystal of the title compound C(10)H(17)NO, synthesized by the reaction of β-cyclo­citral with hydroxyl­amine hydro­chloride, inversion-related mol­ecules are linked by a pair of O—H⋯N hydrogen-bonding inter­actions between the oxime functionalities, forming R (2) (2)(6) loops. The molecular conformation is stabilized by intra­molecular methyl C—H⋯N inter­actions. The cyclohexene ring has the typical half-chair conformation.

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