2,6,6-Trimethyl­cyclo­hexene-1-carbaldehyde oxime

In the crystal of the title compound C(10)H(17)NO, synthesized by the reaction of β-cyclo­citral with hydroxyl­amine hydro­chloride, inversion-related mol­ecules are linked by a pair of O—H⋯N hydrogen-bonding inter­actions between the oxime functionalities, forming R (2) (2)(6) loops. The molecular...

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Autores principales: Parthasarathy, Rajasekaran, Jenniefer, Samson Jegan, Muthiah, Packianathan Thomas, Sulochana, Nagarajan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201277/
https://www.ncbi.nlm.nih.gov/pubmed/22065695
http://dx.doi.org/10.1107/S1600536811037895
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author Parthasarathy, Rajasekaran
Jenniefer, Samson Jegan
Muthiah, Packianathan Thomas
Sulochana, Nagarajan
author_facet Parthasarathy, Rajasekaran
Jenniefer, Samson Jegan
Muthiah, Packianathan Thomas
Sulochana, Nagarajan
author_sort Parthasarathy, Rajasekaran
collection PubMed
description In the crystal of the title compound C(10)H(17)NO, synthesized by the reaction of β-cyclo­citral with hydroxyl­amine hydro­chloride, inversion-related mol­ecules are linked by a pair of O—H⋯N hydrogen-bonding inter­actions between the oxime functionalities, forming R (2) (2)(6) loops. The molecular conformation is stabilized by intra­molecular methyl C—H⋯N inter­actions. The cyclohexene ring has the typical half-chair conformation.
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spelling pubmed-32012772011-11-06 2,6,6-Trimethyl­cyclo­hexene-1-carbaldehyde oxime Parthasarathy, Rajasekaran Jenniefer, Samson Jegan Muthiah, Packianathan Thomas Sulochana, Nagarajan Acta Crystallogr Sect E Struct Rep Online Organic Papers In the crystal of the title compound C(10)H(17)NO, synthesized by the reaction of β-cyclo­citral with hydroxyl­amine hydro­chloride, inversion-related mol­ecules are linked by a pair of O—H⋯N hydrogen-bonding inter­actions between the oxime functionalities, forming R (2) (2)(6) loops. The molecular conformation is stabilized by intra­molecular methyl C—H⋯N inter­actions. The cyclohexene ring has the typical half-chair conformation. International Union of Crystallography 2011-09-30 /pmc/articles/PMC3201277/ /pubmed/22065695 http://dx.doi.org/10.1107/S1600536811037895 Text en © Parthasarathy et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Parthasarathy, Rajasekaran
Jenniefer, Samson Jegan
Muthiah, Packianathan Thomas
Sulochana, Nagarajan
2,6,6-Trimethyl­cyclo­hexene-1-carbaldehyde oxime
title 2,6,6-Trimethyl­cyclo­hexene-1-carbaldehyde oxime
title_full 2,6,6-Trimethyl­cyclo­hexene-1-carbaldehyde oxime
title_fullStr 2,6,6-Trimethyl­cyclo­hexene-1-carbaldehyde oxime
title_full_unstemmed 2,6,6-Trimethyl­cyclo­hexene-1-carbaldehyde oxime
title_short 2,6,6-Trimethyl­cyclo­hexene-1-carbaldehyde oxime
title_sort 2,6,6-trimethyl­cyclo­hexene-1-carbaldehyde oxime
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201277/
https://www.ncbi.nlm.nih.gov/pubmed/22065695
http://dx.doi.org/10.1107/S1600536811037895
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