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(E)-N′-(3-Bromo-5-chloro-2-hy­droxy­benzyl­idene)nicotinohydrazide

There are two independent mol­ecules in the asymmetric unit of the title compound, C(13)H(9)BrClN(3)O(2), in which the dihedral angles between the benzene and pyridine rings are 8.23 (9)° and 52.84 (12)°. Both the mol­ecules exist in an E configuration with respect to the C=N double bond. The two mo...

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Autores principales: Prabhu, M., Parthipan, K., Ramu, A., Chakkaravarthi, G., Rajagopal, G.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201283/
https://www.ncbi.nlm.nih.gov/pubmed/22065830
http://dx.doi.org/10.1107/S1600536811038268
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author Prabhu, M.
Parthipan, K.
Ramu, A.
Chakkaravarthi, G.
Rajagopal, G.
author_facet Prabhu, M.
Parthipan, K.
Ramu, A.
Chakkaravarthi, G.
Rajagopal, G.
author_sort Prabhu, M.
collection PubMed
description There are two independent mol­ecules in the asymmetric unit of the title compound, C(13)H(9)BrClN(3)O(2), in which the dihedral angles between the benzene and pyridine rings are 8.23 (9)° and 52.84 (12)°. Both the mol­ecules exist in an E configuration with respect to the C=N double bond. The two mol­ecules in the asymmetric unit are linked via weak C—H⋯O hydrogen bonds. In both the mol­ecules, an intra­molecular O—H⋯N hydrogen bond generate an S(6) graph-set motif. In the crystal, inter­molecular N—H⋯O and C—H⋯O hydrogen bonds generate bifurcated R (1) (2)(7) ring motifs. The crystal packing is further stabilized by weak inter­molecular N—H⋯O, N—H⋯N, C—H⋯O and π–π [centroid–centroid distance 3.615 (2) Å] inter­actions.
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spelling pubmed-32012832011-11-06 (E)-N′-(3-Bromo-5-chloro-2-hy­droxy­benzyl­idene)nicotinohydrazide Prabhu, M. Parthipan, K. Ramu, A. Chakkaravarthi, G. Rajagopal, G. Acta Crystallogr Sect E Struct Rep Online Organic Papers There are two independent mol­ecules in the asymmetric unit of the title compound, C(13)H(9)BrClN(3)O(2), in which the dihedral angles between the benzene and pyridine rings are 8.23 (9)° and 52.84 (12)°. Both the mol­ecules exist in an E configuration with respect to the C=N double bond. The two mol­ecules in the asymmetric unit are linked via weak C—H⋯O hydrogen bonds. In both the mol­ecules, an intra­molecular O—H⋯N hydrogen bond generate an S(6) graph-set motif. In the crystal, inter­molecular N—H⋯O and C—H⋯O hydrogen bonds generate bifurcated R (1) (2)(7) ring motifs. The crystal packing is further stabilized by weak inter­molecular N—H⋯O, N—H⋯N, C—H⋯O and π–π [centroid–centroid distance 3.615 (2) Å] inter­actions. International Union of Crystallography 2011-09-30 /pmc/articles/PMC3201283/ /pubmed/22065830 http://dx.doi.org/10.1107/S1600536811038268 Text en © Prabhu et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Prabhu, M.
Parthipan, K.
Ramu, A.
Chakkaravarthi, G.
Rajagopal, G.
(E)-N′-(3-Bromo-5-chloro-2-hy­droxy­benzyl­idene)nicotinohydrazide
title (E)-N′-(3-Bromo-5-chloro-2-hy­droxy­benzyl­idene)nicotinohydrazide
title_full (E)-N′-(3-Bromo-5-chloro-2-hy­droxy­benzyl­idene)nicotinohydrazide
title_fullStr (E)-N′-(3-Bromo-5-chloro-2-hy­droxy­benzyl­idene)nicotinohydrazide
title_full_unstemmed (E)-N′-(3-Bromo-5-chloro-2-hy­droxy­benzyl­idene)nicotinohydrazide
title_short (E)-N′-(3-Bromo-5-chloro-2-hy­droxy­benzyl­idene)nicotinohydrazide
title_sort (e)-n′-(3-bromo-5-chloro-2-hy­droxy­benzyl­idene)nicotinohydrazide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201283/
https://www.ncbi.nlm.nih.gov/pubmed/22065830
http://dx.doi.org/10.1107/S1600536811038268
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