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(E)-N′-(3-Bromo-5-chloro-2-hydroxybenzylidene)nicotinohydrazide
There are two independent molecules in the asymmetric unit of the title compound, C(13)H(9)BrClN(3)O(2), in which the dihedral angles between the benzene and pyridine rings are 8.23 (9)° and 52.84 (12)°. Both the molecules exist in an E configuration with respect to the C=N double bond. The two mo...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201283/ https://www.ncbi.nlm.nih.gov/pubmed/22065830 http://dx.doi.org/10.1107/S1600536811038268 |
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author | Prabhu, M. Parthipan, K. Ramu, A. Chakkaravarthi, G. Rajagopal, G. |
author_facet | Prabhu, M. Parthipan, K. Ramu, A. Chakkaravarthi, G. Rajagopal, G. |
author_sort | Prabhu, M. |
collection | PubMed |
description | There are two independent molecules in the asymmetric unit of the title compound, C(13)H(9)BrClN(3)O(2), in which the dihedral angles between the benzene and pyridine rings are 8.23 (9)° and 52.84 (12)°. Both the molecules exist in an E configuration with respect to the C=N double bond. The two molecules in the asymmetric unit are linked via weak C—H⋯O hydrogen bonds. In both the molecules, an intramolecular O—H⋯N hydrogen bond generate an S(6) graph-set motif. In the crystal, intermolecular N—H⋯O and C—H⋯O hydrogen bonds generate bifurcated R (1) (2)(7) ring motifs. The crystal packing is further stabilized by weak intermolecular N—H⋯O, N—H⋯N, C—H⋯O and π–π [centroid–centroid distance 3.615 (2) Å] interactions. |
format | Online Article Text |
id | pubmed-3201283 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32012832011-11-06 (E)-N′-(3-Bromo-5-chloro-2-hydroxybenzylidene)nicotinohydrazide Prabhu, M. Parthipan, K. Ramu, A. Chakkaravarthi, G. Rajagopal, G. Acta Crystallogr Sect E Struct Rep Online Organic Papers There are two independent molecules in the asymmetric unit of the title compound, C(13)H(9)BrClN(3)O(2), in which the dihedral angles between the benzene and pyridine rings are 8.23 (9)° and 52.84 (12)°. Both the molecules exist in an E configuration with respect to the C=N double bond. The two molecules in the asymmetric unit are linked via weak C—H⋯O hydrogen bonds. In both the molecules, an intramolecular O—H⋯N hydrogen bond generate an S(6) graph-set motif. In the crystal, intermolecular N—H⋯O and C—H⋯O hydrogen bonds generate bifurcated R (1) (2)(7) ring motifs. The crystal packing is further stabilized by weak intermolecular N—H⋯O, N—H⋯N, C—H⋯O and π–π [centroid–centroid distance 3.615 (2) Å] interactions. International Union of Crystallography 2011-09-30 /pmc/articles/PMC3201283/ /pubmed/22065830 http://dx.doi.org/10.1107/S1600536811038268 Text en © Prabhu et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Prabhu, M. Parthipan, K. Ramu, A. Chakkaravarthi, G. Rajagopal, G. (E)-N′-(3-Bromo-5-chloro-2-hydroxybenzylidene)nicotinohydrazide |
title | (E)-N′-(3-Bromo-5-chloro-2-hydroxybenzylidene)nicotinohydrazide |
title_full | (E)-N′-(3-Bromo-5-chloro-2-hydroxybenzylidene)nicotinohydrazide |
title_fullStr | (E)-N′-(3-Bromo-5-chloro-2-hydroxybenzylidene)nicotinohydrazide |
title_full_unstemmed | (E)-N′-(3-Bromo-5-chloro-2-hydroxybenzylidene)nicotinohydrazide |
title_short | (E)-N′-(3-Bromo-5-chloro-2-hydroxybenzylidene)nicotinohydrazide |
title_sort | (e)-n′-(3-bromo-5-chloro-2-hydroxybenzylidene)nicotinohydrazide |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201283/ https://www.ncbi.nlm.nih.gov/pubmed/22065830 http://dx.doi.org/10.1107/S1600536811038268 |
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